Chapter 4: Carbon Flashcards
The backbone of life
Carbon
T/F Water is unparalleled in its ability to form molecules that are large, complex, and diverse
False. Carbon is.
How many valences does Carbon have?
4
T/F Organic chemistry is the study of carbon compounds
True
Vitalism
living organisms are fundamentally different from non-living entities because they contain some non-physical element or are governed by different principles than are inanimate things
Living organisms are fundamentally different from non-living entities because they contain some non-physical element or are governed by different principles than are inanimate things.
Vitalism
This experiment tested whether complex organic molecules could arise spontaneously under conditions thought to have existed on the early Earth
Miller’s Experiment
Miller’s experiment proposed that these three compounds made up primitive air. What compounds actually made up air?
CH4, NH3, H20 —-> CO2, N2
Miller’s experiment: the scientists proposed that no ______ existed, when in fact:
Problem with premise
oxygen, oxygen did exist. Since oxygen did (apparently) exist, amino acids would be broken down
Miller’s experiment: amino acid isolation was caused by: , when in actuality _________.
Problem with premise:
cold trap, amino acids would have been destructed, spark will destroy amino acids
T/F Ethylene and Ethene are the same compound
True
Remember: to find valence electrons, Herbert says to add up all the electrons (atomic number) and then add them to orbitals (2, 8, 8, 8)
Truth
Carbon atoms can form diverse molecules by bonding to ____ other atoms
Four
What type of valence does Carbon have?
tetravalence
The arrangement of Carbon’s four ____ ______ causes the bonds to angle toward the corners of an imaginary tetrahedron
hybrid orbitals
Know the structure of Urea
NH2 - CO - NH2
Carbon molecular diversity arises from carbon _____ variation
skeleton
These carbon molecules are composed of only carbon and hydrogen
Hydrocarbons
Name two uses of hydrocarbons
fossil fuels like gasoline
fat
Are hydrocarbons hydrophilic or hydrophobic
Hydrophobic (fat, for example)
Do hydrocarbons release or absorb energy?
Release energy
Isomers are _______ that have the same numbers of atoms of the same ________but different structures and hence, different ______
compounds, elements, properties
Name three types of isomers
structural, geometric, enantiomer
This type of isomer differs in the covalent arrangement of two molecule’s atoms
Structural isomer
Pentane and 2-methyl butane
structural isomer
Cis-trans isomers:
geometric isomers
Each of two or more compounds which differ from each other in the arrangement of groups with respect to a double bond, ring, or other rigid structure.
Geometric isomers
Each of a pair of molecules that are mirror images of each other.
Enantiomers
A form of isomerism in which molecules with the same molecular formula have different bonding patterns and atomic organization
structural isomers