Chapter 4: Atoms and Light Flashcards

1
Q

What are the 6 characteristics of atoms?

A

1.Possess mass
2. Contain positive nuclei
3. Contain electrons
4. Occupy volume
5. Attract one another
6. Combine to form molecules

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2
Q

The best tool for studying the structure of atoms is?

A

Electromagnetic radiation

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3
Q

Wavelength (y)

A

The distance between two successive crests

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4
Q

Frequency (v)

A

The number of waves passing a certain point over a unit of time

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5
Q

Amplitude

A

The height of the wave measured from the axis of propagation, a measure of intensity

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6
Q

What is the photoelectric effect?

A

Below a threshold frequency, no electrons are observed, regardless the intensity of light

Above the threshold frequency, the number of emitted electrons increases with the intensity of the light

All metals show the same pattern, but each metal has a different threshold frequency

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7
Q

What are the two properties of light?

A
  1. Wave-like
  2. Particle-like
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8
Q

What are photons?

A

Packets of energy

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9
Q

Electrons are only ejected if…

A

The frequency of light is high enough

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10
Q

Is the ejection of electrons dependent on the intensity of light?

A

No

The greater the intensity, the more photons but if no photon has enough energy to remove an electron, none will be ejected

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11
Q

What is photoionization?

A

The ejection of an electron

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12
Q

What is an excited state?

A

When an atom absorbs a photon

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13
Q

What is the ground state?

A

Lowest energy state of an atom

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14
Q

What is absorption spectrum?

A

Measures the frequencies of photons that an atom absorbs

Very colourful. The dark bands = light absorbed by the sample

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15
Q

What is an emission spectrum?

A

The intensity of light as a function of frequency
Dark. The colour represents the photons emmited

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16
Q

What did Niels Bohr discover?

A

That electrons can only occupy certain energy levels

17
Q

What are the 3 properties of electrons?

A
  1. Each electron has the same mass and charge
  2. Electrons behave like magnets
  3. Electrons have wave properties
18
Q

What is Heisenberg’s Uncertainty Principle?

A

The more accurately we know an electrons position, the more uncertain we are about motion, and vice versa

We identify a “probable location” of the electrons in an atom

19
Q

What does the Principle Quantum Number represent? (n)

A

The quantized energy of an atomic electron

Corresponds to an electron “shell”

19
Q

What does the Azimuthal Quantum Number (l) represent?

A

The shapes of atomic orbitals
n-1

0=s
1=p
2=d
3=f

20
Q

What does the Magnetic Quantum Number represent? (ml)

A

The different orientations of the orbitals
-l-+l

21
Q

What does the Spin Orientation Quantum Number represent? (ms)

A

The direction
Magnetism is directional so, ms= +1/2 or -1/2

22
Q

What do orbitals describe?

A

The delocalization of electrons

23
Q

Each orbital becomes _____ as nuclear charge increases

A

Smaller

24
Q

In any atom, are orbitals with the same principle quantum number similar sizes?

A

Yes

25
Q

What shape are all s orbitals?

A

Spherical

26
Q

How many possible p-orbitals are there?

A

3

27
Q

How many possible d-orbitals are there?

A

5

28
Q

How many possible f-orbitals are there?

A

7

28
Q

How does ozone protect the earth from harmful radiation?

A

It absorbs UV light

29
Q

What is the greenhouse gas effect?

A

CO2 absorbs and remits infra-red radiation, which overtime, increases the earth’s average temperature