Chapter 4 - Alkanes Flashcards

1
Q

Parent Name for 1 Carbon

A

Methane

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2
Q

Substituent Name for 1 Carbon

A

Methyl

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3
Q

Parent Name for 2 Carbons

A

Ethane

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4
Q

Substituent Name for 2 Carbons

A

Ethyl

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5
Q

Parent Name for 3 Carbons

A

Propane

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6
Q

Substituent Name for 3 Carbons

A

Propyl

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7
Q

Parent Name for 4 Carbons

A

Butane

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8
Q

Substituent Name for 4 Carbons

A

Butyl

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9
Q

Parent Name for 5 Carbons

A

Pentane

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10
Q

Parent Name for 5 Carbons

A

Pentyl

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11
Q

Parent Name for 6 Carbons

A

Hexane

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12
Q

Substituent Name for 6 Carbons

A

Hexyl

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13
Q

Substituent Name for 7 Carbons

A

Heptyl

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14
Q

Parent Name for 7 Carbons

A

Heptane

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15
Q

Parent Name for 8 Carbons

A

Octane

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16
Q

Substituent Name for 8 Carbons

17
Q

Parent Name for 9 Carbons

18
Q

Substituent Name for 9 Carbons

19
Q

Parent Name for 10 Carbons

20
Q

Substituent Name for 10 Carbons

21
Q

Isobutyl Structure

A

Substituent with two branches on second carbon

22
Q

Secbutyl Structure

A

Substituent with two branches on first carbon

23
Q

Tert-butyl Structure

A

Substituent with three branches on first carbon

24
Q

Torsional Strain

A

strain from eclipsing Hydrogen atoms, creating a less stable molecule

25
Steric Strain
strain from large, identical, eclipsing substitute groups
26
Angle Strain
strain from angles diverging away from the optimal 109.5° of a tetrahedral formation
27
What is the amount of energy in one C-H diaxial interaction?
3.8 kJ/mol
28
Describe the stability between the two chair conformations of a cis-1,2-dimethylcyclohexane
Both conformations are equally stable because they each have one axial methyl group and one equatorial methyl group
29
Describe the stability between the two chair conformations of a cis-1,3-dimethylcyclohexane
Both conformations are NOT equally stable because one conformation has two axial methyl groups and the other has two equatorial methyl groups *The conformation with two equatorial methyl groups is more stable*
30
Describe the stability between the two chair conformations of a cis-1,4-dimethylcyclohexane
Both conformations are equally stable because they each have one axial methyl group and one equatorial methyl group
31
Describe the stability between the two chair conformations of a trans-1,2-dimethylcyclohexane
Both conformations are NOT equally stable because one conformation has two axial methyl groups and the other has two equatorial methyl groups *The conformation with two equatorial methyl groups is more stable*
32
Describe the stability between the two chair conformations of a trans-1,3-dimethylcyclohexane
Both conformations are equally stable because they each have one axial methyl group and one equatorial methyl group
33
Describe the stability between the two chair conformations of a trans-1,4-dimethylcyclohexane
Both conformations are NOT equally stable because one conformation has two axial methyl groups and the other has two equatorial methyl groups *The conformation with two equatorial methyl groups is more stable*