Chapter 4 - Alkanes Flashcards

1
Q

Parent Name for 1 Carbon

A

Methane

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2
Q

Substituent Name for 1 Carbon

A

Methyl

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3
Q

Parent Name for 2 Carbons

A

Ethane

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4
Q

Substituent Name for 2 Carbons

A

Ethyl

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5
Q

Parent Name for 3 Carbons

A

Propane

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6
Q

Substituent Name for 3 Carbons

A

Propyl

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7
Q

Parent Name for 4 Carbons

A

Butane

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8
Q

Substituent Name for 4 Carbons

A

Butyl

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9
Q

Parent Name for 5 Carbons

A

Pentane

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10
Q

Parent Name for 5 Carbons

A

Pentyl

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11
Q

Parent Name for 6 Carbons

A

Hexane

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12
Q

Substituent Name for 6 Carbons

A

Hexyl

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13
Q

Substituent Name for 7 Carbons

A

Heptyl

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14
Q

Parent Name for 7 Carbons

A

Heptane

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15
Q

Parent Name for 8 Carbons

A

Octane

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16
Q

Substituent Name for 8 Carbons

A

Octyl

17
Q

Parent Name for 9 Carbons

A

Nonane

18
Q

Substituent Name for 9 Carbons

A

Nonyl

19
Q

Parent Name for 10 Carbons

A

Decane

20
Q

Substituent Name for 10 Carbons

A

Decyl

21
Q

Isobutyl Structure

A

Substituent with two branches on second carbon

22
Q

Secbutyl Structure

A

Substituent with two branches on first carbon

23
Q

Tert-butyl Structure

A

Substituent with three branches on first carbon

24
Q

Torsional Strain

A

strain from eclipsing Hydrogen atoms, creating a less stable molecule

25
Q

Steric Strain

A

strain from large, identical, eclipsing substitute groups

26
Q

Angle Strain

A

strain from angles diverging away from the optimal 109.5° of a tetrahedral formation

27
Q

What is the amount of energy in one C-H diaxial interaction?

A

3.8 kJ/mol

28
Q

Describe the stability between the two chair conformations of a cis-1,2-dimethylcyclohexane

A

Both conformations are equally stable because they each have one axial methyl group and one equatorial methyl group

29
Q

Describe the stability between the two chair conformations of a cis-1,3-dimethylcyclohexane

A

Both conformations are NOT equally stable because one conformation has two axial methyl groups and the other has two equatorial methyl groups

The conformation with two equatorial methyl groups is more stable

30
Q

Describe the stability between the two chair conformations of a cis-1,4-dimethylcyclohexane

A

Both conformations are equally stable because they each have one axial methyl group and one equatorial methyl group

31
Q

Describe the stability between the two chair conformations of a trans-1,2-dimethylcyclohexane

A

Both conformations are NOT equally stable because one conformation has two axial methyl groups and the other has two equatorial methyl groups

The conformation with two equatorial methyl groups is more stable

32
Q

Describe the stability between the two chair conformations of a trans-1,3-dimethylcyclohexane

A

Both conformations are equally stable because they each have one axial methyl group and one equatorial methyl group

33
Q

Describe the stability between the two chair conformations of a trans-1,4-dimethylcyclohexane

A

Both conformations are NOT equally stable because one conformation has two axial methyl groups and the other has two equatorial methyl groups

The conformation with two equatorial methyl groups is more stable