Chapter 4 Flashcards

1
Q

Adsorbed cations are also known as ____.

A

exchangeable cations

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2
Q

What is the charge of agriculturally important soils?

A

negative charge

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3
Q

The process whereby cations adsorbed on the surface of soil colloids is exchanged for those in the soil solution or in any medium that comes in contact with the soil colloids.

A

Cation exchange

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4
Q

If nutrients are not absorbed by soil colloids, they are subject to what.

A

Loss through leaching

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5
Q

Na-rich soils are in what state?

A

dispersed

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6
Q

The element that is responsible in dispersing soil.

A

Na

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7
Q

Ca-rich soils make the soil to be?

A

flocculated

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8
Q

Element responsible in making flocculated soil

A

Ca

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9
Q

Is dispersion a desirable characteristic of productive soil?

A

NOT desirable

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10
Q

The CEC of permanent charge clays.

A

low CEC

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11
Q

The buffering capacity of permanent charge clays?

A

low buffering capacity

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12
Q

Accompanying ions

A

complementary ions

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13
Q

What will happen to the ion of interest if the complementary ion is strongly adsorbed?

A

easily released

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14
Q

The quantitative measure of the ability of soil to adsorb and exchange cations with those in the surrounding solution and with plant roots.

A

cation exchange capacity

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15
Q

The sum of the negative charges of the soil.

A

cation exchange capacity

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16
Q

The sum total of the exchangeable cations that a soil can adsorb.

A

cation exchange capacity

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17
Q

The easily exchangeable cations.

A

electrostatically retained cations

18
Q

The cations that are readily available for plant uptake.

A

electrostatically retained cations

19
Q

The dissociation of H from OH- groups

A

deprotonation

20
Q

What will happen to the charge if there is deprotonation?

A

additional negative charge

21
Q

What is the CEC of OM?

A

100-300 cmolc/kg soil

22
Q

Tells us the degree to which the exchange sites are occupied by basic cations.

A

percentage base saturation

23
Q

Give examples of basic cations.

A

K
Ca
Mg
Na

24
Q

Give examples of acidic cations.

A

Al
H

25
Q

The atomic weight of Ca.

A

40 g/mol

26
Q

The atomic weight of Na.

A

23g/mol

27
Q

The atomic weight of K?

A

39g/mol

28
Q

The atomic weight of Mg.

A

24g/mol

29
Q

What will happen to the cations if there is high percentage cation saturation?

A

easily and rapidly released

30
Q

Enumerate the practical applications of CEC.

A

plant nutrition
liming
amelioration of Na affected soil
environmental quality

31
Q

Enumerate the soil properties that determine CEC.

A

soil texture
organic matter content
nature of clay colloid
pH
percentage base saturation

32
Q

Enumerate the methods of determining CEC.

A

CEC determination at pH7 ammonium acetate:1N
calculation of effective CEC
CC determination using BaCl2

33
Q

Enumerate the soil processes that affect cation exchange.

A

weathering
nutrient retention
dispersion and flocculation
buffering pH change

34
Q

The characteristics of cation exchange reactions

A

ER are stoichiometric and take place in equivalent amounts
CE are instantaneous
ER are reversible

35
Q

Factors affecting the extent of cation exchange.

A
  1. Relative adsorbability of the cation on soil colloid or the relative replacing the power of the cation
  2. Concentration of the solution
  3. Nature of exchange materials
  4. Geometric fit of ions into the mineral structure
  5. Influence of complementary ions
36
Q

Between Kaolinite and Illite which has a rapid cation exchange?

A

Kaolinite

37
Q

Between kaolinite and illite which takes longer time?

A

illite

38
Q

High level of Ca is antagonistic to?

A

inhibit K

39
Q

High K would lead to

A

interfere Mg

40
Q

ESP stands for

A

Exchangeable Sodium Percentage

41
Q

Soils with high amounts of soluble sodium

A

Sodic soils