Chapter 38 Flashcards
Rutherford proposed the βnuclear modelβ of the atom, which
posited a small positively charged nucleus surrounded by electrons.
Bohr assumption:
he assumed that electrons can only orbit at certain discrete (i.e. quantized) distances from the nucleus:(π=1, π=2, π=3, ππ‘π.)
Bohr assumption:
he assumed that electrons can only orbit at certain discrete (i.e. quantized) distances from the nucleus:(π=1, π=2, π=3, ππ‘π.)
electric potential energy for electron in an atom
Potential Energy: The work done by a conservative force
The work done by a conservative force is defined as producing a change in
potential energy
Electric potential energy
Using the following definitions of work, show that an electron gains 1 ππ of potential energy when it moves across a 1 π capacitor
Potential Energy (of an Electron)
Electron Transitions
- When electrons transition from a higher orbit (higher energy state) to a lower orbit (lower energy state), a photon is emitted with energy πΈ=βπ.
- This energy is equal to the electronβs change in energy:
πΈ_βππββπΈ_πππ€=πΈ_πβππ‘ππ
The Lyman series is due to
πΎ π‘ππππ ππ‘ππππ
- The Balmer series is due to πΏ π‘ππππ ππ‘ππππ
- Note how the ΞπΈ for the Balmer series are of the order of 1 ππ. Remember that a photon of frequency in the visible light range has an energy of β1ππ (πΈ=βπ)
Spectrum of solar radiation
Total energy of an electron on shell n:
As an electron transitions between energy levels, from π_ππππ‘πππ to π_πππππ, energy is released as EM radiation.
From ni to nf, the energy released is:
The expression for the wavelength of the emitted photon during an electron transition (in H)
where π is the Rydberg constant