Chapter 38 Flashcards
Rutherford proposed the “nuclear model” of the atom, which
posited a small positively charged nucleus surrounded by electrons.
Bohr assumption:
he assumed that electrons can only orbit at certain discrete (i.e. quantized) distances from the nucleus:(𝑛=1, 𝑛=2, 𝑛=3, 𝑒𝑡𝑐.)
Bohr assumption:
he assumed that electrons can only orbit at certain discrete (i.e. quantized) distances from the nucleus:(𝑛=1, 𝑛=2, 𝑛=3, 𝑒𝑡𝑐.)
electric potential energy for electron in an atom
Potential Energy: The work done by a conservative force
The work done by a conservative force is defined as producing a change in
potential energy
Electric potential energy
Using the following definitions of work, show that an electron gains 1 𝑒𝑉 of potential energy when it moves across a 1 𝑉 capacitor
Potential Energy (of an Electron)
Electron Transitions
- When electrons transition from a higher orbit (higher energy state) to a lower orbit (lower energy state), a photon is emitted with energy 𝐸=ℎ𝑓.
- This energy is equal to the electron’s change in energy:
𝐸_ℎ𝑖𝑔ℎ−𝐸_𝑙𝑜𝑤=𝐸_𝑝ℎ𝑜𝑡𝑜𝑛
The Lyman series is due to
𝐾 𝑡𝑟𝑎𝑛𝑠𝑖𝑡𝑖𝑜𝑛𝑠
- The Balmer series is due to 𝐿 𝑡𝑟𝑎𝑛𝑠𝑖𝑡𝑖𝑜𝑛𝑠
- Note how the Δ𝐸 for the Balmer series are of the order of 1 𝑒𝑉. Remember that a photon of frequency in the visible light range has an energy of ≈1𝑒𝑉 (𝐸=ℎ𝑓)
Spectrum of solar radiation
Total energy of an electron on shell n:
As an electron transitions between energy levels, from 𝑛_𝑖𝑛𝑖𝑡𝑖𝑎𝑙 to 𝑛_𝑓𝑖𝑛𝑎𝑙, energy is released as EM radiation.
From ni to nf, the energy released is:
The expression for the wavelength of the emitted photon during an electron transition (in H)
where 𝑅 is the Rydberg constant