Chapter 38 Flashcards

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1
Q

Rutherford proposed the “nuclear model” of the atom, which

A

posited a small positively charged nucleus surrounded by electrons.

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2
Q

Bohr assumption:

A

he assumed that electrons can only orbit at certain discrete (i.e. quantized) distances from the nucleus:(𝑛=1, 𝑛=2, 𝑛=3, 𝑒𝑡𝑐.)

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3
Q

Bohr assumption:

A

he assumed that electrons can only orbit at certain discrete (i.e. quantized) distances from the nucleus:(𝑛=1, 𝑛=2, 𝑛=3, 𝑒𝑡𝑐.)

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4
Q

electric potential energy for electron in an atom

A
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5
Q

Potential Energy: The work done by a conservative force

A
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6
Q

The work done by a conservative force is defined as producing a change in

A

potential energy

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7
Q

Electric potential energy

A
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8
Q

Using the following definitions of work, show that an electron gains 1 𝑒𝑉 of potential energy when it moves across a 1 𝑉 capacitor

A
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9
Q

Potential Energy (of an Electron)

A
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10
Q

Electron Transitions

A
  • When electrons transition from a higher orbit (higher energy state) to a lower orbit (lower energy state), a photon is emitted with energy 𝐸=ℎ𝑓.
  • This energy is equal to the electron’s change in energy:
    𝐸_ℎ𝑖𝑔ℎ−𝐸_𝑙𝑜𝑤=𝐸_𝑝ℎ𝑜𝑡𝑜𝑛
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11
Q

The Lyman series is due to

A

𝐾 𝑡𝑟𝑎𝑛𝑠𝑖𝑡𝑖𝑜𝑛𝑠

  • The Balmer series is due to 𝐿 𝑡𝑟𝑎𝑛𝑠𝑖𝑡𝑖𝑜𝑛𝑠
  • Note how the Δ𝐸 for the Balmer series are of the order of 1 𝑒𝑉. Remember that a photon of frequency in the visible light range has an energy of ≈1𝑒𝑉 (𝐸=ℎ𝑓)
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12
Q

Spectrum of solar radiation

A
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13
Q

Total energy of an electron on shell n:

A
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14
Q

As an electron transitions between energy levels, from 𝑛_𝑖𝑛𝑖𝑡𝑖𝑎𝑙 to 𝑛_𝑓𝑖𝑛𝑎𝑙, energy is released as EM radiation.
From ni to nf, the energy released is:

A
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15
Q

The expression for the wavelength of the emitted photon during an electron transition (in H)

A

where 𝑅 is the Rydberg constant

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