Chapter 3- Bonding Flashcards
molecular orbitals
form when two atomic orbitals combine
hybridization
way of making all the bonds to a central atom equivalent to each other
hybrid orbitals
hybrid orbitals are formed by mixing different types of orbitals. use math to mix the following orbitals:
sp3
sp2
sp
sp3
1 atom with all single bonds (sigma bonds).
tetrahedral geometry and no unhybridized p-orbitals to form pi bonds.
sp2
1 double bond (1 sigma and 1 pi bond).
seen in alkenes. third orbital of each carbon is left unhybridized.
sp
triple bond (1 sigma and 2 pi bonds)
to form a triple bond (alkynes). linear structure.
resonance
describes delocalization of electrons in molecules that have conjugated bonds
pi bond
formed by the parallel overlap of unhybridized p-orbitals