Chapter 3: Biological molecules Flashcards

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1
Q

anions

A

*Nitrate - Nitrogen supply to plants and protein formation
*Hydrogen carbonate - maintenance of blood pH
*Chloride - balance sodium and potassium ions in cells
* Phosphate - cell membrane formation, nucleic acid and ATP formation, bone formation
Hydroxide - Catalysts and pH determination

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2
Q

cations

A

Calcium - Nerve impulses and muscle contraction
Sodium - Nerve impulse transmission and kidney function
Potassium - Nerve impulse transmission and stomatal opening
Hydrogen - catalysis of reactions and pH determination
Ammonia - Production of nitrate ions by bacteria

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3
Q

water

A

water is important as:
*its a metabolite
*able to do electrolysis

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4
Q

props of water?

A

*excellent solvent
*High SHC
*High latent heat of vaporisation
*less dense when solid
*high surface tension and cohesion
*acts as a reagent

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5
Q

water (2)

A

*104.5 bond angle
*covalent bond
*it is a polar molecule as it has charge but is specifically a dipole meaning it has both a slight negative and slight positive charge
*oxygen has the slight negative charge
hydrogen has the slight positive charge
*oppositely charged atoms on each molecule are attracted to eachother and form hydrogen bonds

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6
Q

glucose

A

*a hexose monosaccharide
*fundamental within carbs

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7
Q

glycosidic bonds

A

*formed by condensation reaction which produces water
*broken by hydrolisis

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8
Q

alpha-glucose

A

starch:
*amylose - straight chain therefore only 1-4 glycosidic bonds
*amylopectin - has branches aswell so has 1-4 and 1-6 glycosidic bonds
Glycogen (animals) : like amylopectin but more branched
-Branched means that it can be more compact and therefore more stable

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9
Q

carbohydrates

A

a group of substances used as both energy sources and structural materials in organisms
*carbohydrates - H,O,C element atoms only

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10
Q

monosaccharides

A

*monosaccharides are simple: galactose, fructose, glucose
* they are bonded together in a condensation reaction to form disaccharides
* bond formed is a glycosidic bond

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11
Q

disaccharides formed from monosaccharides

A

maltose: 2 x glucose
sucrose: glucose and fructose
lactose: glucose and galactose

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12
Q

What’s the general formula of carbohydrates?

A

Cx(H2O)y

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13
Q

What’s the bond angle of water?

A

104.5

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14
Q

Where is the OH group on a glucose which is different to b glucose?

A

Alpha has OH on bottom on first carbon whereas Beta has OH on top of first carbon.

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15
Q

What reaction is it called when a glycosidic bond is formed?

A

Condensation reaction and water is released

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16
Q

What type of bond is a glycosidic bond?

A

Covalent bond

17
Q

What is starch?

A

Many alpha glucose molecules joined by glycosidic bonds.
Glucose which is stored in plants is known as starch.

18
Q

What is amylose?

A

Is a polysaccharide in starch.
Is formed by alpha glucose molecules and only has 1-4 glycosidic bonds.
Is much more compact as it forms a helix shape.

19
Q

What is amylopectin?

A

Is the other polysaccharide of starch.
Contains 1-4 and 1-6 glycosidic bonds.
1-6 glycosidic bonding means amylopectin has branches.
1-6 branch occurs approximately every 25 glucose sub units

20
Q

What is glycogen?

A

Is the functionally equivalent storage molecule to starch in animals and fungi.
Forms more branches than amylopectin, therefore is more compact and this is ideal for storage.

21
Q

What are the key properties of amylopectin and glycogen?

A

They are insoluble, branched and compact

22
Q

How is glucose released from starch or glycogen for respiration?

A

They undergo hydrolysis.
Is catalysed by enzymes.

23
Q

What is cellulose made from and how?

A

Cellulose is made from Beta glucose molecules.
Every other beta glucose molecule is inverted so that condensation reactions between the oh groups can occur.

24
Q

How are cellulose fibres formed from cellulose molecules?

A

Cellulose molecules form hydrogen bonds with each other to form microfibrils.
Microfibrils join to form macrofibrils.
Macrofibrils combine to produce cellulose fibres.

25
Q

What do cellulose fibres make?

A

Cell wall

26
Q

What are properties of cellulose fibres?

A

Strong and insoluble

27
Q

How do you test for reducing sugars? What is the positive test result?

A

1) place sample in boiling tube. If not liquid, grind it up and mix with water.
2) add equal vol of Benedict’s reagent
3) heat gently in boiling water bath for 5 mins

Blue to brick red

28
Q

How do you test for non reducing sugars using Benedict’s?

A

Same as reducing sugars but has to be boiled with dilute HCl first.

29
Q

How do you test for starch using iodine? What is the positive result?

A

Dissolve a few drops of iodine solution with potassium iodide.

Yellow to purple/black

30
Q

What is another way to test for reducing sugars?

A

Manufactured reagent test strips

31
Q

What are fats?

A

Fats are lipids that are solid at room temp

32
Q

What are oils?

A

Are lipids that are liquid at room temp

33
Q

Are lipids polar or non polar?

A

Non polar and so insoluble in water

34
Q

What is a triglyceride made from?

A

A glycerol and three fatty acid tails.

35
Q

What are the bonds between a glycerol and fatty acid tails called? What is the reaction called?

A

The bonds are ester bonds and the reaction is called esterification.

36
Q

What is esterification an example of

A

A condensation reaction.

37
Q

How much water is used when triglycerides are broken down? What is the reaction called?

A

Three water molecules are released.
Hydrolysis