Chapter 21 - Nuclear Chemistry Flashcards

0
Q

Atomic number

A

Number of protons

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1
Q

Nucleons

A

Protons, neutrons, electrons

Nucleus is composed of the first two

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2
Q

Mass of atom

A

Number of protons and neutrons

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3
Q

Isotopes happen because

A

Varying neutrons

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4
Q

Radioactive

A

Unstable

Not uncommon for nuclides aka radionuclides

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5
Q

Alpha decay

A

Loss of an alpha particle (a helium nucleus)

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6
Q

Beta decay

A

Loss of the beta particle (a high energy electron)

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7
Q

Positron emission

A

Nuclei decay by emitting a positron a particle hay has the same mass as but and opposites charge to that of an electron
0
e
1

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8
Q

Gamma emission

A

The loss of a gamma ray which is high energy radiation that almost always accompanies the loss of a nuclear particle
0
0

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9
Q

Electron capture

A

Addition of an electron to a proton in the nucleus

Result is a neutron

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10
Q

Neutron-proton ratios

A

Any element with more than one proton will have repulsions between the protons in the nucleus

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11
Q

What helps keep the nucleus from flying apart?

A

A strong nuclear force

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12
Q

Neutrons key role

A

Stabilizing the nucleus

The ratio of neutrons to protons is an important factor

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13
Q

For smaller nuclei the neutron - proton ratio

A

Is close to 1:1 when z< 21

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14
Q

As nuclei get larger the number of neutrons needed to stabilize the nucleus

A

Increases

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15
Q

Belt of stability

A

Blue dark dots that show what nuclides would be stable

16
Q

Above the belt of stability

A

Above the belt have too many neutrons (tend to be emitting beta particles)

17
Q

Below the belt of stability

A

Nuclei have too many protons

Can become more stable by positron emission or electron capture

18
Q

There are no stable nuclei with an atomic number greater than

A

83

These nuclei tend to decay by alpha emission

19
Q

Large radioactive nuclei and stabilization

A

Cannot stabilize from one nuclear transformation

Undergo a series of decays often forming a nuclide of lead

20
Q

Trends of number of protons and neutrons dealing with stability

A

Even is more stable than odds

21
Q

How can one tap all the energy of a nucleus

A

Nuclear fission

Starts with the bombardment with a neutron which causes the decay and production of more neutrons (nuclear chain reaction)

22
Q

Critical mass

A

Rate of neutron loss = rate of neutron creation by fission

23
Q

Manhattan project

A

Development of the a bomb in WWII

Lead by Oppenheimer and groves

Used uranium 235

24
Q

Curie/becquerel

A

Amt of radiation emitted by material

25
Q

Rad/gray

A

Radiation dose absorbed by a person

26
Q

Rem/sievert

A

Biological risk of exposure to radiation

27
Q

Geiger counter

A

Used to measure the amount of activity present in radioactive sample

Detects current of ions

28
Q

Kinetics of radioactive decay

A

Nuclear transmutation is a first order process

Kinetics of such a process obey this eqn: ln(Nt/N0) = -kt

29
Q

Half life of radioactive decay

A

0.693/k

30
Q

Radiocarbon dating

A

By comparing amount of a radioactive nuclide present at a given point in time with the amount normally present we can find the age of an object

31
Q

Nuclear reactors

A

In nuclear reactors the heat generated by the reaction is used to produce steak that turns a turbine connected to a generator

Reaction is kept in check by control rods by blocking the paths of some neutrons

32
Q

Nuclear accidents

A

Three mile island
Chernobyl
Fukushima

33
Q

How can nuclear transformations be induced

A

By acceleration a particle and colliding it with the nuclide

34
Q

Particle accelerator

A

Enormous
Circular tracks
Radii is miles long

35
Q

Nuclear fusion

A

Superior method of generating power

Products not reactive
To achieve fusion the material must be state of plasma (super hot)