Chapter 21 naming Flashcards
Carboxylic acid derivates are defined as compounds with functional groups that can be converted to carboxylic acids by a simple acidic or basic _______
hydrolysis
- Nitrile, acid halide, acid anhydride, ester, amide
What is the functional suffix for a R≡N
-nitrile
What is the functional suffix for Ring-C≡N (attached to a nonbenzene ring)
carbonitrile
What is the functional suffix for a RCONR’2
-amide
What is the functional suffix for Ring-CONR’2 (attached to a nonbenzene ring)
carboxamide
What is the functional suffix for a RCOOR (ester)
-oate
What is the functional suffix for Ring-COOR (attached to a nonbenzene ring)
carboxylate
What is the functional suffix for an acid anhydride
-oic anhydride
- if its symmetrical then one name if its unsymmetrical then 2 names
What is the functional suffix for acid anhydride (inside a nonbenzene ring)
dioic anhydride
- root is how many carbons in the ring
What is the functional suffix for a RCOCl (acid chloride)
-oyl chloride
What is the functional suffix for Ring-COCl (attached to a nonbenzene ring)
carbonyl chloride
benzoic acid derivatives:
nitrile: _______
benzonitrile
benzoic acid derivatives:
amide: _______
benzamide
- substituents on N have N position
benzoic acid derivatives:
ester: _______
benzoate
- space before benzoate and substituent
benzoic acid derivatives:
anydride: _______
benzoic anhydride
benzoic acid derivatives:
acid chloride: _______
benzoyl chloride
What is the order of the functional group priority chart?
Carboxylic acids
Esters
Amides
Nitriles
Aldehydes
Ketones
Alcohols
Amines
Alkenes
alkynes
alkanes
ethers
halides
_______ are cyclic esters. Named by adding the term _______ at the end of the name of the parent carboxylic acid
lactone
lactone
- IUPAC name of CA derivative then add lactone
_______ are cyclic amides. Named by adding the term _______ at the end of the name of the parent carboxylic acid
lactam
lactam
ex) 3-aminopropanoic acid lactam
