Chapter 20: Gases Flashcards

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1
Q

What is the pressure of a gas?

A

The force per unit area that the gas exerts normally on a surface. Pressure is measured in pascals 1PA = 1Nm-1

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2
Q

What does Boyle’s Law state?

A

For a fixed mass of gas at a constant temperature,

pV = constant

where p is gas pressure and v is volume

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3
Q

What does Charles Law state?

A

For a fixed mass gas at constant pressure varies with absolute temperature,

V/T = constant
The graph is a straight line going through the origin.

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4
Q

What does the pressure Law state?

A

The pressure of a fixed mass of gas at constant volume can be measured at different temperatures.

P/T = constant

If the measurements are plotted, on a graph of pressure against temperature in kelvin s they give a straight line graph through the origin.

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5
Q

What is Brownian motion?

A

The unpredictable motion of particles suspended in a medium as a result of continuous bombardment by their surroundings.

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6
Q

What is avogadro constant?

A

Avogradros constant NA The number of atoms in exactly 12g of the carbon isotope 12C6. The value of NA is 6.023 x 10^23

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7
Q

What is one atomic mass unit?

A

1/12th of the mass of a 12C^ atom. The mass of a carbon atom is 1.993x10-26 so 1u = 1.661 x 10^-27

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8
Q

What is one mole

A

The quantity of substance that contains NA particles, the number of moles in a give quantity of the substance is its molarity. The unit of molarity is the mol

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9
Q

What is molar mass?

A

The mass of 1 mol of the substance, the unit of molar mass is kg mol-1. For example, the molar mass of oxygen gas is 0.032kgmol^-1

Number of moles in a substance Ms/M where M is the molar mass

The number of molecules in mass Ms of a substance NAMs/M

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10
Q

What is the ideal gas and its equation?

A

An ideal gas is a gas that obeys Boyle’s law perfectly The three laws can be combined to give pV/T = constant for a fixed mass of ideal gas

pV = nRT

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11
Q

What is a molar gas constant?

A

Molar gas constant R = For q mol of any ideal gas, the value of PV/T is equal to 8.31 Jmol-1K-1

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12
Q

What is the equation to calculate number of moles?

A

Ms - mass
M - molar mass
n = number of moles

Ms = M x n

n also = PV/RT

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13
Q

How to calculate mass of a ideal gas?

A

Ms = M x pV/RT

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14
Q

How to calculate density of an ideal gas of molar M

A

p = Ms/V

or NM/V

or pM/RT

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15
Q

What is Boltzmann constant?

A

Boltzmann constant k = R/NA, and N is the number of molecules. It relates the average kinetic energy of a particle in a gas with the temperature of the gas.

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16
Q

Explain pressure law

A

The pressure law can be explained as follows. The pressure of a gas
at constant volume is increased by raising its temperature. The average
speed of the molecules is increased by raising the gas temperature.
Therefore, the impacts of the molecules on the container walls are
harder and more frequent. So the pressure is raised as a result.

17
Q

What assumptions are made in kinetic theory equation?

A
  • The molecules are point molecules. The volume of each molecule
    is negligible compared with the volume of the gas.
  • They do not attract each other. If they did, the effect would be to
    reduce the force of their impacts on the container surface.
  • They move about in continual random motion.
  • The collisions they undergo with each other and with the
    container surface are elastic collisions (i.e., there is no overall loss
    of kinetic energy in a collision).
  • Each collision with the container surface is of much shorter
18
Q

What does Adiabetic mean?

A

No temperature or energy is lost, closed system

19
Q

What does Isobaric mean?

A

Pressure is constant

20
Q

What does Isothermic mean?

A

Temperature is constant

21
Q

What is the relationship between PV and T

A

PV is directly proportional to T, however, P is inversely proportional to V

22
Q

How do you change from 1 mole to mols

A

Multiply by avogradro constant NA

23
Q

What is Raved?

A

The assumptions that the Kinetic theory of gases follows

R - Random motion
A - No attraction between particles ( bounce without sticking)
V - Particles/molecules have negative value
E - Elastic collisions take place, kinetic energy is conserved
D - Duration of collisions must be very short compared to the time between collisions

The molecules are point molecules. The volume of each molecule
is negligible compared with the volume of the gas.
They do not attract each other. If they did, the effect would be to
reduce the force of their impacts on the container surface.
They move about in continual random motion.
The collisions they undergo with each other and with the
container surface are elastic collisions (i.e., there is no overall loss
of kinetic energy in a collision).
Each collision with the container surface is of much shorter
duration than the time between impacts.

24
Q

use physics and math tutor flashcards as well

A
25
Q
A
26
Q

What is the equation for 1st law of Thermodynamics?

A

Q = Δu + w

Where Q is heat supplied by gas
W = work done by gass
u = change in internal energy

27
Q

What happens in an Isothermal process?

A

The temp is same so Δu = 0 since internal energy isnt changing

therefore

Q = W

P1V1 = P2V2

28
Q

What happens in an Adiabetic process?

A

No heat is lost or gaineed so Q = 0

terefore Δu = -W

29
Q

What happens if volume is constant?

A

There will be no work done. W = 0

W = pΔV if constant P

30
Q

What is the gradient of a pressure- volume graph?

A

Work done