Chapter 20 - Acids, bases and pH Flashcards

1
Q

What is a Brønsted-Lowry acid?

A

A proton donor.

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2
Q

What is a Brønsted-Lowry base?

A

A proton acceptor.

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3
Q

What is a conjugate acid-base pair?

A

Two species that can be interconverted by transfer of a proton.

The formula of the acid and base in a conjugate acid-base pair differs by H+.

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4
Q

What is a monobasic acid?

A

An acid in which each molecule can release one proton.

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5
Q

What is a dibasic acid?

A

An acid in which each molecule can release two protons.

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6
Q

What is a tribasic acid?

A

An acid in which each molecule can release three protons.

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7
Q

What is the acid dissociation constant, Ka?

A

The equilibrium constant that measures the extent of acid dissociation.

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8
Q

The larger the value of Ka, the _______ the pKa value and the ________ the acid.

A

The larger the value of Ka, the smaller the pKa value and the stronger the acid.

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9
Q

Water can acts as an ____ or a ____.

A

Water can acts as an acid or a base.

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10
Q

The larger the value of [H+], the _______ the pH value and the more _____ the solution is.

A

The larger the value of [H+], the smaller the pH value and the more acidic the solution is.

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11
Q

What is an important rule to remember about strong monobasic acids?

A

[H+] = [HA]

A strong acid completely dissociates.

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12
Q

What is the ionic product of water?

A

Kw = [H+] [OH-]

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13
Q

In all aqueous solutions, H+(aq) and OH-(aq) are both present.
When [H+] = [OH-]…
When [H+] > [OH-]…
When [H+] < [OH-]…

A

…a solution is neutral.
…a solution is acidic.
…a solution is alkaline.

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14
Q

For a strong monobasic base…

A

[OH-] = [Base]

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15
Q

If you are given [Base] and temperature as 25°C or 298K, you can calculate [H+] using _____.

A

If you are given [Base] and temperature as 25°C or 298K, you can calculate [H+] using Kw.

The value of Kw at 298K is given in the data sheet.

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16
Q

What is a limitation of using weak acid approximations to Ka related calculations for ‘stronger’ weak acids?

A

[HA]equilibrium ~ [HA]undissociated may no longer be

valid.