Chapter 2: Elements and the periodic table Flashcards
What is an isotope?
An element that contain equal numbers of protons but different numbers of neutrons
What are the three subatomic particles
Protons, neutrons and electrons
What is an atom
The building blocks of matter
What is a molecule?
A group of two or more atoms covalently bonded
What is an ion?
A charged atom
Shell configuration vs subshell configuration
The shell configuration is the amount of electrons per shell (e.g 2,8,8,1). Subshell configuration is an electron configuration that uses the subshells and blocks on the periodic table (e.g 1s^2 2s^2 2p^6)
List the differences from the Bohr and Schrödinger model
Bohr:
- cannot accurately predict the emission spectra of atoms with more than one
electron
- is unable to explain why electron shells can only hold 2n^2 electrons
- does not explain ,why the fourth shell accepts two electrons before the third shell
is completely filled.
Schrödinger:
- there are major energy levels in atom called shells
- these shells contain seperate energy levels called subshells
- each subshell is made up of orbitals. They can be described as regions of space surrounding the nucleus of an atom in which electrons may be found. Any orbital can hold a maximum of two electrons.
What are critical elements?
Critical elements are elements that are heavily relied on in industry and society in areas such as renewable energy, electronics, food supply and medicine. Some critical elements include copper, gold and tin.
List six trends in the periodic table
- Electronegativity
- Atomic Radii
- First Ionisation Energy
- Core Charge
- Metallica Character
- Non-Metallic Character
What is electronegativity?
Electronegativity is the ability to attract electrons to itself.
Describe the trends for electronegativity on the periodic table
When going left to right on the periodic table, electronegativity increases because the valence electrons are less strongly attracted to the nucleus as they are further away from the nucleus.
When going down a group on the periodic table, electronegativity decreases because the valence electrons become more strongly attracted to the nucleus as the core charge increases the valence electrons become more strongly attracted to the nucleus
What is atomic radii?
Atomic radius is a measurement used for the size of atoms. It can be regarded as the distance from the nucleus to the valence shell electrons
Describe the trends for atomic radii on the periodic table
When going left to right on the periodic table, atomic radii decreases because the core charge increases.
When going down a group on the periodic table, the atomic radii increase because there are more shells
What is core charge?
The core charge (effective nuclear charge) of an atom is a measure of the attractive force felt by the valence shell electrons towards the nucleus.
What is the formula for core charge?
Core charge = number of protons in the nucleus - number of total inner shell electrons
Describe the trends of core charge on the periodic table
When going left to right on the periodic table, core charge increases because the valence electrons are more attracted to the nucleus
When going down a group on the periodic table, core charge remains constant because valence electrons are held less strongly because they are further away from the nucleus.
What is first ionisation energy?
The energy required to remove one electron from an atom of an element in the gas phase
Describe the trends of first ionisation energy on the periodic tale
When going left to right on the periodic table, first ionisation energy increases because the core charge increases.
When going down a group on the periodic table, first ionisation energy decreases the valence electrons are less attracted to the nucleus because they are away from the nucleus
What is metallic character?
Metallic character refers to the level of reactivity of a metal
Describe the trend of metallic character on the periodic table
When going left to right on on the periodic table, the metallic character decreases because of the tendency of atoms to lose or gain electrons when going across a period
When going down a group on the periodic table, the metallic character increases The metallic character of an element depends on how readily it can lose its electrons and since the size of an atom increases causing a lesser attraction between the nuclei and the electrons
What is nonmetallic character?
Non-metallic character relates to the tendency to accept electrons during chemical reactions.
Describe the trends of the non-metallic character on the periodic table
When going left to right on the periodic table, the nonmetallic character increases because it is easier to gain electrons when moving left to right
When going down a group on the periodic table, the nonmetallic character decreases because it becomes more difficult to gain electrons
Describe the reactivity of metals and non-metals in relation to the periodic table
For metals, the more down you go down a group, the weaker electrostatic force between nucleus and electrons, but the more reactive
For non-metals, the more down you go down a group, the the weaker electrostatic force between nucleus and electrons but less reactive