Chapter 2 - Carbon-Based Fuels Flashcards
Activation Energy
The energy required to break the bonds of the reactants in a chemical reaction.
Biodiesel
A mixture of organic compounds (esters), formed from vegetable oils through a process called transesterification.
Bioethanol
Ethanol - C2H5OH - formed from the fermentation of glucose obtained from plants (mainly sugar cane, wheat & forest waste).
Biogas
A mixture of carbon dioxide and methane formed during the anaerobic (“without oxygen”) decomposition of organic material (e.g. sewage).
Biomass
Organic matter (e.g. plant & animal waste) that is used as a fuel (e.g. biogas).
Cellular Respiration
The process through which cells in the body extract energy from glucose according to the equation:
C6H12O6(aq) + 6O2(g) → 6CO2(g) +6H2O(l) ; ∆H = -2803 kJ
Chemical Energy
The energy stored in the bonds of chemical compounds, made up of its kinetic energy (movement) and potential energy (e.g. gravitational, magnetic, etc).
Combustion
The burning of a fuel in oxygen to form carbon dioxide and water.
Fuel + Oxygen → Carbon Dioxide + Water
Complete Combustion
Combustion in an excess of oxygen, forming carbon dioxide.
Distillation
The process of purifying an aqueous solution by boiling and cooling a mixture.
Endothermic
A reaction that absorbs energy (e.g. dissolving), resulting in a decreased temperature. H(products) > H(reactants). i.e. ∆H > 0.
Energy Profile Diagram
A graph illustrating the energy of a reaction as time progresses. Energy is absorbed to break bonds and released to make bonds.
Enthalpy (H)
The heat content of a substance. Note: can’t be directly measured, only the change in enthalpy (∆H).
Enthalpy of Combustion (∆Hc)
(Also ‘heat of combustion’) The heat energy released when one mole of a substance burns completely in oxygen.
Exothermic
A reaction that releases energy (e.g. combustion), resulting in an increased temperature. H(products) < H(reactants). i.e. ∆H < 0.
Fermentation
The process through which a substance is broken down by a microorganism or enzyme. Used to create bioethanol.
Fossil Fuel
A non-renewable fuel formed from dead biological material (e.g. coal, oil, natural gas).
Fuel
A substance with stored chemical energy which can be easily released for heat or power.
Hydrocarbon
A compound containing hydrogen and carbon, such as methane (CH4).
Incomplete Combustion
Combustion in an insufficient supply of oxygen, forming carbon monoxide (CO) or carbon soot (C).
Joule
The unit for energy.
Natural Gas
A fossil fuel consisting mainly of methane, with small amounts of ethane and propane.
Photosynthesis
The process through which plants convert the sun’s energy into chemical potential energy according to the formula:
CO2(g) +6H2O(l) → C6H12O6(aq) + 6O2(g) ; ∆H = +2803 kJ
Thermochemical Equation
A balanced chemical equation which displays the enthalpy value of the reaction. e.g. CH4(g) + 2O2(g) → CO2(g) +2H2O(l) ; ∆H = -890 kJ
System
The chemical reaction taking place (e.g. combustion).
Surrondings
The area around a chemical reaction (e.g. air, water, etc).
Fermentation of Glucose Equation
C6H12O6(aq) → 2C2H5OH(aq) + 2CO2(g)
Note: then needs to be distilled for combustion
Energy Content (kJ/g)
The amount of energy in a mixture (e.g. foods). Cannot have enthalpy calculated since they do not have a molar mass.