Chapter 2 - Atoms, Ions, Molecules Flashcards
Atomic Symbol
Used to represent an atom corresponding to a particular element
Dalton’s Atomic Theory
- Each element is composed of tiny, indestructible particles called atoms
- All atoms of a given element have the same mass and other properties that distinguish them from atoms of other elements
- Atoms combine simple, whole-number ratios to form molecules of compounds
- In a chemical reaction, atoms of one element cannot change into atoms of another element. They simply rearrange the way they are attached
Subatomic Particles of Atoms and their Charges
Protons(+)
Electrons(-)
Neutrons(neutral)
Rutherford’s Model of Atomic Structures
Atom = dense, heavy nucleus at center
Nucleus contains protons and neutrons (both make up nearly entire mass of atom)
Nucleus surrounded by electron cloud
JJ Thomson (1856-1940)
Discovered electrons in 1897 using a cathode-ray tube
Cathode-Ray Tube
Consists of glass tube where most if the air was removed.
Used by JJ Thomson to discover electrons
Plum Pudding Model (of atom)
Idea of a positively charged nucleus and the negatively charged electrons distributed throughout the positively charged sphere
Robert Millikan (1868-1953)
Determines the charge of electron through oil drop experiment
Henri Becquerel (1896)
Discovered radioactivity
Noticed that some materials produced invisible radiation consisting of charged particles
Radioactivity
Spontaneous emission of high energy radiation particles (beta, alpha particles)
Beta Particles (B)
High energy electrons (negatively charged)
Alpha Particles (a)
Positively charged (+2) Mass= He nucleus
Atomic Mass Unit (amu)
Unit used to express relative masses of atoms and subatomic particles
1amu = 1/12 of carbon atom
(Carbon made up of 6protons 6neutrons)
1amu = 1 Dalton (Da)
Dalton (Da)
1 Da = 1 amu
Francis W. Aston (1877-1945)
Used charged beam of neon (Ne+) and noticed 2 signals which meant 2 different isotopes
Discovered isotopes
Isotopes
Atoms of an element containing the same number of protons but different neurons
Ex. neon
1 isotope has 10 neutrons in it’s nucleus and a mass of 20amu
Another isotope has 12 neutrons and a mass of 22amu (protons remain the same)
Nuclides
Each individual isotope with a particular combo of protons and neutrons
Atomic Number
Number of protons in the nucleus
Determines identity of element
Atomic Mass Number
Total number of nucleons (protons & neutrons) in nucleus
Average Atomic Mass
Weighted average of masses of all isotopes of an element
Calculated by multiplying natural abundance by its mass (im amu) and then summing these products
Natural Abundance
Proportion of a particular isotope; usually expressed as a percentage relative to all isotopes for that element
(How much of each isotope exists in relative to the other isotopes existing for that element)
Only non-decaying stable isotopes occur naturally and therefore have natural abundance
Dimitri Mendeleev (1834-1907)
1872 - published a periodic table
Ordered elements by increasing atomic mass (in modern: ordered by atomic numbers)
Arranged elements in columns based on similar chemical & physical properties
Left open spaces for elements not yet discovered
Based on the locations of the empty cells he was able to predict the chemical and physical properties
Modern Period Table
Elements classified according to physical and chemical properties (like Mendeleev)
Horizontal Rows= periods (1-7)
Columns= groups- contain elements of the same family (or group) (1-18)
Alkali Metal
Group 1
Have 1 valence electron (want to lose electron)
Shiny, soft metals, highly reactive
Do not occur naturally as free elements
Reactivity increases down the group(as outer electron gets further from nucleus and becomes easier to remove)
By losing electron they become cation and stable
Alkaline Earth Metal
Group 2
2 valence electrons
Harder, denser, stronger than alkali
Have higher melting points than alkali
Lower reactivity than alkali
React with water to form metal hydroxides
Anion
Negatively charged particle created when an atom or molecule gains one or more electrons
Cation
Positively charged particle created when an atom or molecule loses one or more electrons
Carboxylic acid
Organic compound containing -COOH functional group
Covalent Bond
A bond between two atoms created by SHARING one or more electrons
2 nonmetals
Law of Multiple Proportions
The ratio of the two masses of one element react with a given mass of another element to form two different compounds is the ratio of two small numbers
Molecular Compound
Composed of atoms held together in molecules by covalent bonds (nonmetals)
Molecular Formula
Shows the # and type of atoms present in one molecule of a compound
Empirical Formula
Shows the smallest whole number ratio of elements in a compounds
Ionic Compounds
Consist of charged particles (ions) formed by transfer of electrons between atoms
(Between metals and nonmetals)
CH3COO-
Acetate
NH4+
Ammonium
N3-
Azide
Br-
Bromide
CO3 2-
Carbonate
ClO3-
Chlorate
Cl-
Chloride
CrO4 2-
Chromate
CN-
Cyanide
Cr2O7 2-
Dichromate
H2PO4-
Dihydrogen Phosphate
S2 2-
Disulfide
F-
Fluoride
H-
Hydride
HCO3-
Hydrogen Carbonate
or
Bicarbonate
HPO4 2-
Hydrogen Phosphate
HSO3-
Hydrogen sulfite or bisulfite
OH-
Hydroxide
NO3-
Nitrate
N 3-
Nitride
NO2-
Nitrite
O2-
Oxide
ClO4-
Perchlorate
MnO4-
Permanganate
O2 2-
Peroxide
PO4 3-
Phosphate
SO4 2-
Sulfate
S2 -
Sulfide
SO3 2-
Sulfite
SCN-
Thiocyanate
Naming Binary MOLECULAR Compounds
(contain 2 nonmetals)
- Name first element
- Change ending of name of second element to -ide
- Add prefixes to first & second names to indicate # of atoms (do not use mono on first element)
Naming Binary IONIC Compounds
(Contain cations (metals) & anions (nonmetals))
- Name metal (cation)
- Name nonmetal (anion) with ending changed to ide
Transition metals - use roman numeral to indicate charge
Naming Binary ACIDS
- Add prefix hydro-
2. Replace last syllable in name with suffix -ic & add acid at the end