chapter 2 Flashcards

1
Q

what does a lewis structure show ?

A

the arrangement of electrons and bonds in a molecule or polyatomic ion

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2
Q

if the difference of EN > 1.7

A

ionic

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3
Q

if the difference of EN < 1.7 > 0.5

A

polar covalent

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4
Q

if the difference of EN < 0.5

A

non-polar covalent

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5
Q

in ionic bonds, the valence electrons are

A

transferred

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6
Q

in polar covalent bonds, the valence electrons are

A

shared unequally (partial charges)

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7
Q

in non polar covalent bonds, the valence electrons are

A

shared equally

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8
Q

what are ions formed and held together by ?

A

electrostatic attraction

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9
Q

atoms and ions are stable if they have

A

a full valence shell of electrons

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10
Q

electrons are most stable when

A

paired

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11
Q

atoms form chemical bonds to

A

achieve a full valence shell

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12
Q

a full valence shell may be achieved by either

A

transferring or sharing electrons

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13
Q

what are the 3 types of ionic compounds ?

A

binary ionic compounds
polyatomic ionic compounds
ionic compounds with multivalent metals

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14
Q

binary ionic compounds (how many ? what do they end in ?)

A

2 elements: 1 metal and 1 non-metal

end in -ide

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15
Q

polyatomic compounds (how many ? what do they end in ?)

A

more than 2 elements: 1 metal and 1 polyatomic ion

compound names usually end in -ate or -ite

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16
Q

compounds with multivalent metals

A

contain a metal with more than one possible charge

roman numerals indicate charge

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17
Q

which compounds use roman numerals to indicate charge ?

A

multivalent metals

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18
Q

what kind of compounds do NOT criss cross charges ?

A

molecular/covalent compounds

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19
Q

covalent/molecular compounds contain, end in ?

A

contain 2 or more non-metals

end in -ide

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20
Q

what kind of compounds use prefixes ?

A

molecular/covalent

hydrates

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21
Q

list the prefixes

A
mono
di
tri
tetra
penta
hexa
hepta
octo
nona
deca
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22
Q

what are the two types of acids ?

A

binary acids

oxy acids

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23
Q

what are binary acids composed of ?

A

H and one other element

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24
Q

what are oxy acids composed of ?

A

H and a polyatomic ion

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25
all acids are
aq
26
what kind of acids start with hydro-
binary acids
27
give an example of a binary acid
hydrochloric acid
28
binary acids end in
-ic
29
when writing acids, for polyatomic ions that end in -ate, the acid ends in
-ic
30
when writing acids, for polyatomic ions that end in -ite, the acid ends in
-ous
31
what does VSEPR stand for ?
valence shell electron pair repulsion
32
who developed the VSEPR theory ?
Ronald Gillespie and Ronald Nyholm
33
what is the VSEPR theory ?
a model for predicting the shape of molecules
34
what is important for molecular shape ?
the valence shell electrons of the central atoms
35
what do valence shell electron pairs do ?
they repel each other electrostatically
36
what determines the molecular shape ?
the positions of the electron pairs when they are a maximum distance apart (with the lowest repulsion possible)
37
what do geometrical arrangements refer to ?
refers to the ways in which the groups of valence electrons are positioned around the central atom
38
how many basic geometrical arrangements and what do they result from ?
there are 5 basic geometrical arrangements | result from the interactions of lone pairs and bonding of electrons
39
list the 5 basic geometrical arrangements ?
``` linear trigonal planar tetrahedral trigonal bipyramidal octahedral ```
40
variations in the molecular shape occur if
one or more of the electron groups include a lone pair of electrons
41
2 bonds (0 lp) = 2
linear
42
3 bonds (0 lp) = 3
trigonal planar
43
4 bonds (0 lp) = 4
tetrahedral
44
5 bonds (0 lp) = 5
trigonal bipyramidal
45
6 bonds (0 lp) = 6
octahedral
46
2 bonds 1 lp = 3
bent
47
3 bonds 1 lp = 4
trigonal pyramidal
48
2 bonds 2 lp = 4
bent
49
4 bonds 1 lp = 5
sawhorse
50
3 bonds 2 lp = 5
t-shaped
51
2 bonds 3 lp = 5
linear
52
5 bonds 1 lp = 6
square pyramidal
53
4 bonds 2 lp = 6
square planar
54
overall polarity of a molecule depends on
``` dipole moments (location of partial charges) molecular shape ```
55
in order for a molecule to be POLAR, it must have..
polar covalent bonds | nonsymmetrical partial charge distribution
56
what determines the melting and boiling points of a compound ?
the strength of the force between ions or molecules
57
____ compounds usually have HIGH mp and bp
ionic
58
____ compounds have intermediate mps and bps
polar covalent
59
____ molecules have the lowest mp and bp
non polar covalent
60
water is a _____ molecule
polar
61
what kind of compounds are insoluble in water ?
non polar covalent compounds
62
what kind of compounds are soluble in water ?
ionic and polar covalent
63
in order to conduct an electric current, ions must
be free to move
64
which state of ionic compounds can conduct electricity ?
liquid and aqueous
65
what are INTERmolecular forces ?
attractions between molecules
66
what are INTRAmolecular forces ?
forces within molecules
67
which forces are stronger, intermolecular or intramolecular ?
intramolecular forces are stronger
68
intermolecular forces as a group are referred to as
van der waals forces