Chapter 2 Flashcards

1
Q

How did Leucippus, Democritus, and Aristotle conceptualize atoms?

A

According to Leucippus and Democritus the world is made up of two fundamental elements, atoms and the void. They believed atoms to be the smallest unit of matter, thus making them indivisible. In their model, atoms make up all physical objects and are uniform. Aristotle famously rejected atomism in On Generation and Corruption.

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2
Q

What are the postulates of Dalton’s Atomic Theory?

A

A theory of chemical combination, first stated by John Dalton in 1803. It involves the following postulates: (1) Elements consist of indivisible small particles (atoms). (2) All atoms of the same element are identical; different elements have different types of atom. (3) Atoms can neither be created nor destroyed.

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3
Q

How is Dalton’s Atomic Theory consistent with the Law of Conservation of Mass?

A

That mass can neither be created nor be destroyed.

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4
Q

What does the Law of Definite Proportions tell us?

A

The law of definite proportions states that a given chemical compound always contains the same elements in the exact same proportions by mass.

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5
Q

What does the Law of Multiple Proportions tell us?

A

The law of multiple proportions states that whenever the same two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers.

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6
Q

What did Thomson discover with the results of his cathode ray experiments?

A

Thomson’s experiments with cathode ray tubes showed that all atoms contain tiny negatively charged subatomic particles or electrons.

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7
Q

What information came from Millikan’s oil drop experiment?

A

The oil drop experiment allowed Millikan to determine the charge on the electron. He later used this data to determine the mass of the electron.

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8
Q

What were the features of the atom models proposed by JJ Thomson and Hantaro Nagaoka?

A

Thomson, a British scientist, discovers the electron. The later leads to his “plum-pudding” model. He pictures electrons embedded in a sphere of positive electrical charge. Hantaro Nagaoka, a Japanese physicist, suggests that an atom has a central nucleus.

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9
Q

What were the results of Rutherford’s gold foil experiments, and how did this disprove earlier models of the atom?

A

Rutherford’s gold foil experiment showed that the atom is mostly empty space with a tiny, dense, positively-charged nucleus. Based on these results, Rutherford proposed the nuclear model of the atom.

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10
Q

What model did Rutherford propose based on his experiments?

A

Based on these results, Rutherford proposed the nuclear model of the atom.

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11
Q

What discovery did Frederick Soddy make about the masses of elements?

A

In 1913, he was the first to announce the concept that atoms can be identical chemically and yet have different atomic weights.

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12
Q

How did Chadwick account for the non-proton mass in the nucleus?

A

Using the kinetic energy and momentum of emitted protons, Chadwick showed that the mass of a neutron is slightly greater than that of a proton.

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13
Q

What are the charges and relative sizes of the different subatomic particles?

A

The size of the charges is the same, but the sign is opposite. Protons have a charge of +1, neutrons have a charge of 0, and electrons have a charge of -1.

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14
Q

How is an atomic mass unit (amu) defined?

A

AMU is defined as one-twelfth the mass of an atom of carbon-12 (12C). 12. C is the most abundant natural carbon isotope, accounting for over 98% of carbon found in nature. It has an AMU of 12.

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15
Q

What property defines what element an atom is?

A

The number of protons in the nucleus determines which element an atom is, while the number of electrons surrounding the nucleus determines which kind of reactions the atom will undergo.

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16
Q

What is the atomic number of an atom?

A

The atomic number of an atom is the total number of protons in the nucleus of the atom. The atomic number is denoted with the symbol Z.

17
Q

What is an isotope? How does the concept of natural abundance relate to isotopes?

A

Atoms that have the same number of protons but different numbers of neutrons are known as isotopes. Isotopes have different atomic masses. The relative abundance of an isotope is the percentage of atoms with a specific atomic mass found in a naturally occurring sample of an element.

18
Q

What is the difference between and atomic number and a mass number? How are they denoted?

A

The atomic number is the number of protons in an element, while the mass number is the number of protons plus the number of neutrons.

19
Q

How can the number of protons, neutrons and electrons be determined from the mass number and chemical symbol?

A

You can simply subtract the atomic number from the mass number in order to find the number of neutrons. If the atom is neutral, the number of electrons will be equal to the number of protons.

20
Q

What is an ion? How is the charge of an ion denoted?

A

An atom or group of atoms that carries a positive or negative electric charge as a result of having lost or gained one or more electronsThe charge of an ion is indicated by a plus (+) or minus sign (-), which is written to the right of and just above the ion’s chemical symbol.

21
Q

What distinguishes and anion from a cation?

A

Cations are positively-charged ions (atoms or groups of atoms that have more protons than electrons due to having lost one or more electrons). Anions are negatively-charged ions (meaning they have more electrons than protons due to having gained one or more electrons).

22
Q

Why is it necessary to use an average atomic mass?

A

The average atomic mass is useful because its numerical value is equal to the molar mass of the element.

23
Q

How can an average atomic mass be calculated?

A

The average atomic mass of an element is the sum of the masses of its isotopes, each multiplied by its natural abundance.

24
Q

What information is conveyed by both a molecular and a structural formula?

A

A molecular formula and a structural formula both convey the same information about a compound:
The types and numbers of atoms in the molecule
The actual number of atoms for each element that is present in a compound
A structural formula also conveys the following information:
The spatial arrangement of the atoms
Which atoms are bonded to each other
Whether each bond is single, double, or triple
How the atoms are organized
The chemical bonds between the atoms

25
Q

What is the empirical formula?

A

Empirical formulas show the simplest whole-number ratio of atoms in a compound, molecular formulas show the number of each type of atom in a molecule, and structural formulas show how the atoms in a molecule are bonded to each other.

26
Q

What is a mole and why is it used?

A

A mole is a very important unit of measurement that chemists use. A mole of something means you have 602,214,076,000,000,000,000,000 of that thing, like how having a dozen eggs means you have twelve eggs. Chemists have to measure using moles for very small things like atoms, molecules, or other particles.