Chapter 19 reaactions

Question 1

Base catalyzed hydration reagents

Answer 1

Carbonyl group and hydrozide

Question 2

Base catalyzed hydration steps

Answer 2

NA, H+ transfer

Question 3

Acid catalyzed hydration reagents

Answer 3

Carbonyl group, acid

Question 4

Acid catalyzed hydration steps

Answer 4

H+, NA, H+

Question 5

Base catalyzed hydration product

Answer 5

Carbonyl changed into 2 OH with 2H bonded to them

Question 6

Acid catalyzed hydration product

Answer 6

Carbonyl changed into 2 OH with 2H bonded to them

Question 7

Acetyl formation reagents

Answer 7

Alcohol, adehyde/ketone

Question 8

Acetyl formation steps

Answer 8

2H+NA, LLG, NA, H+

Question 9

Acetyl formation product

Answer 9

Acetyl (1 C with 2RO bound to it, 2 CH3)

Question 10

Imine definition

Answer 10

Compound with C=N

Question 11

Imine reagents

Answer 11

Aldehyde/ketone with primary amine

Question 12

Imine steps

Answer 12

NA, 3H+, LLG, H+

Question 13

Imine products

Answer 13

Imine

Question 14

Enamine reagents

Answer 14

Aldehyde/ketone and 2ndary amine in acidic conditions

Question 15

Enamine steps

Answer 15

NA, 3 H+, LLG, H+

Question 16

Enamine product

Answer 16

nitrogen atom directly connected to a carbon-carbon π bond.

Question 17

Wolff Krishner reduction reagents

Answer 17

Hydrazone (C=NH2), base

Question 18

Wolff Krishner reduction steps

Answer 18

3H+, LLG, H+

Question 19

Wolff Krishner reduction products

Answer 19

Alkane chain

Question 20

Hydrolysis of acetyls reagents

Answer 20

Acetyl, acid

Question 21

Hydrolysis of acetyls steps

Answer 21

H+, LLG, NA, 2H+, LLG, H+

Question 22

Hydrolysis of acetyls products

Answer 22

Ketone

Question 23

Ketone/aldehyde with hydride agents

Answer 23

K/A with hydride reducing agent (LiAlH4, 2. H3O+ or water) (Or NaBH4, MEOH)