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Organic Chemistry 2 > Chapter 17 > Flashcards

Chapter 17 Flashcards

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1
Q

What are the 5 Class 1 Carbonyls?

A

Carboxylic Acid, Ester, Anhydride, Acylhalide and Amide

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2
Q

What are the 2 Class 2 Carbonyls?

A

Aldehyde and Ketone

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3
Q

Name the compound:

A

Propanoic Acid

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4
Q

Name the compound:

A

3-Ethyl-2-methylpentanoic Acid

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5
Q

Name the compound:

A

3-Flourocyclopentane carboxylic acid

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6
Q

Name the following:

A

heptanedioic Acid

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7
Q

Name the following:

A

Butanoyl Chloride

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8
Q

Name the following:

A

3,3-Dimethylhexanoyl Bromide

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9
Q

Name the following:

A

3-Ethylcyclohexane Carbonyl Chloride

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10
Q

Name the following:

A

Ethanoic Anhydride

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11
Q

Name the following:

A

Ethanoic Methanoic Anhydride

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12
Q

Name the following

A

Methyl Propanoate

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13
Q

Name the following:

A

Phenyl 2,3-Dimethylbutanoate

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14
Q

Name the following:

A

Phenyl Cyclopentane Carboxylate

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15
Q

Name the following:

A

Butanamide

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16
Q

Name the following:

A

N, N -Diethylbutanamide

17
Q

Name the following:

A

N-Cyclopentyl-2-methylbutanamide

18
Q

Name the following:

A

Ethanenitrile

19
Q

Name the following:

A

2-Methylbutanenitrile

20
Q

What is the physical properties of Carbonyls?

A
  • The ability to Hydrogen bond
  • Higher Boiling Point caused by polarity of the carbonyl
21
Q

What are the relative Leaving Groups?

A
22
Q

What are the trends between Good and Horrible leaving group?

A
  • Weaker base is more electronegative, so it is able to stablize the - charge.
  • more electronegative LG = more + carbonyl carbon = more reactive carbonyl
  • weaker base also less likely to resonate w/ carbonyl
23
Q

Show the mechanism below:

A
24
Q

Rxn of ester:

A

H+, H20

25
Q
A

NaOH ,H20

26
Q

Mech of Hydrolysis

A
27
Q

Safonification

A

Organic Chemistry 2 (4 decks)

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