Chapter 17 Flashcards
What are the 5 Class 1 Carbonyls?
Carboxylic Acid, Ester, Anhydride, Acylhalide and Amide
What are the 2 Class 2 Carbonyls?
Aldehyde and Ketone
Name the compound:
Propanoic Acid
Name the compound:
3-Ethyl-2-methylpentanoic Acid
Name the compound:
3-Flourocyclopentane carboxylic acid
Name the following:
heptanedioic Acid
Name the following:
Butanoyl Chloride
Name the following:
3,3-Dimethylhexanoyl Bromide
Name the following:
3-Ethylcyclohexane Carbonyl Chloride
Name the following:
Ethanoic Anhydride
Name the following:
Ethanoic Methanoic Anhydride
Name the following
Methyl Propanoate
Name the following:
Phenyl 2,3-Dimethylbutanoate
Name the following:
Phenyl Cyclopentane Carboxylate
Name the following:
Butanamide
Name the following:
N, N -Diethylbutanamide
Name the following:
N-Cyclopentyl-2-methylbutanamide
Name the following:
Ethanenitrile
Name the following:
2-Methylbutanenitrile
What is the physical properties of Carbonyls?
- The ability to Hydrogen bond
- Higher Boiling Point caused by polarity of the carbonyl
What are the relative Leaving Groups?
What are the trends between Good and Horrible leaving group?
- Weaker base is more electronegative, so it is able to stablize the - charge.
- more electronegative LG = more + carbonyl carbon = more reactive carbonyl
- weaker base also less likely to resonate w/ carbonyl
Show the mechanism below:
Rxn of ester:
H+, H20
NaOH ,H20
Mech of Hydrolysis
Safonification
