Chapter 16 Corrosion and Degradation of Materials Flashcards
Metals and ceramics corrode
polymers degrade
degradation
dissolving when exposed to chemical absorb solvent electromagnetic radiation (primarily ultraviolet light) heat
oxidation
nonmetallic scale or film Metal atoms give up electrons M –> M^n+ + ne-
anode
location where oxidation takes place
reduction reaction
losing the electrons to another chemical compound (oxidation)
cathode
where the reduction occurs
oxidation consequence
- metal ions into corroding solution OR 2. Form an insoluble compound (rust)
oxidation consequence
- metal ions go into corroding solution OR 2. Form an insoluble compound (rust)
anode corrodes
cathode collects?
anode corrodes - cathode collects
“ehn” (shove away) “catch-ode”
standard half-cell
a pure metal electrode immersed in a 1M solution of its ions @25C or 77F
emf
electromotive force
reduction
Metal ions and electrons condensing to metal M^n+ + ne^- –> M
Nernst Equation
Corrosion penetration rate (CPR)
Material removal rate
formula: CPR = KW/rho At