chapter 15 Flashcards
Assumptions for the kinetic theory of gases
large number of molecules in a random motion with a random speed
volume occupied by particles is negligible compared to the volume occupied by the gas
collisions are perfectly elastic and time of collisions is negligible compared to time between collisions
Negligible forces between particles except during collisions
Boyle’s law explained
When mass and temperature are constant:
pV = constant
p is proportional to 1/v
Investigate Boyle’s law
A sealed syringe with gas is connected to a pressure gauge
change the volume to not change the temperature by producing friction
slowly and plot p against v
Charles Law
When mass and volume are constant:
p/T = constant
p is proportional to T
Investigate absolute 0 using Charle’s law
Connect a sealed flask to a pressure gauge
place in a water bath and vary the temperature
you can plot p against temperature in Celsius from x >= 0
extrapolate the straight line to y = 0
all forms of pV
pV - nRT
pV = NKT
pV = 1/3 x Nm C^2
p1V1 = P2 V P2 / TP2 x T1
Deriving the equation shows that the average kinetic energy of the molecules is proportional to the temperature
1/3 Nmc^2 = NKT
cancel N factor out 2/3
1/2 m c ^ 2 = 3/2 KT
Kinetic energy = 1.5 times the boltzmann constant times the temperature
The internal energy of an ideal gas
The internal energy of an ideal gas is equal to the kinetic energy as the electrostatic potential was assumed to be negligible except during collisions