chapter 15 Flashcards

1
Q

Assumptions for the kinetic theory of gases

A

large number of molecules in a random motion with a random speed

volume occupied by particles is negligible compared to the volume occupied by the gas

collisions are perfectly elastic and time of collisions is negligible compared to time between collisions

Negligible forces between particles except during collisions

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2
Q

Boyle’s law explained

A

When mass and temperature are constant:
pV = constant
p is proportional to 1/v

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3
Q

Investigate Boyle’s law

A

A sealed syringe with gas is connected to a pressure gauge
change the volume to not change the temperature by producing friction
slowly and plot p against v

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4
Q

Charles Law

A

When mass and volume are constant:
p/T = constant
p is proportional to T

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5
Q

Investigate absolute 0 using Charle’s law

A

Connect a sealed flask to a pressure gauge
place in a water bath and vary the temperature
you can plot p against temperature in Celsius from x >= 0
extrapolate the straight line to y = 0

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6
Q

all forms of pV

A

pV - nRT
pV = NKT
pV = 1/3 x Nm C^2
p1V1 = P2 V P2 / TP2 x T1

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7
Q

Deriving the equation shows that the average kinetic energy of the molecules is proportional to the temperature

A

1/3 Nmc^2 = NKT
cancel N factor out 2/3
1/2 m c ^ 2 = 3/2 KT
Kinetic energy = 1.5 times the boltzmann constant times the temperature

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8
Q

The internal energy of an ideal gas

A

The internal energy of an ideal gas is equal to the kinetic energy as the electrostatic potential was assumed to be negligible except during collisions

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