Chapter 14 - Thermal Physics Flashcards

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1
Q

Thermal Equilibrium

A

Where two bodies have the same temperature so there is no net flow of energy

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2
Q

Flow of energy

A

Net flow from a hotter object to a colder one until they both have the same temperature

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3
Q

0th law of thermodynamics

A

If 2 objects are each in thermal equilibrium with a third then all 3 must be in thermal equilibrium with each other

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4
Q

Triple point of water

A

0.01C and 0.61kPa, where water exists as all three phases at the same time

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5
Q

Kelvin

A

Has absolute 0 at 0 degrees with the same intervals as degrees celcius

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6
Q

Kelvin formula

A

T(K) = θ(°C) + 273

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7
Q

Solid arrangement

A

Particles regularly arranged and closely packed with strong electrostatic forces holding them in fixed positions, vibrate with kinetic energy

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8
Q

Liquid arrangement

A

Particles very close together but have more kinetic energy so can change position and flow past each other

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9
Q

Gas arrangement

A

More kinetic energy and are much further apart. They are free to move past each other and have negligible electrostatic forces between them unless they collide with each other or the container walls. Move randomly with different speeds and directions

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10
Q

Brownian Motion

A

The seemingly random movement of particles as they move linearly between collisions with other particles and the walls of the container

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11
Q

Internal Energy

A

The sum of the randomly distributed kinetic and potential energies of atoms or molecules within a substance

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12
Q

Internal energy at absolute 0

A

Not equal to 0 as there is an electrostatic potential energy

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13
Q

Internal energy changes

A

Increases as you heat a substance as the kinetic energy increases
Increases with changes from solid to liquid and liquid to gas as the electrostatic forces increase

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14
Q

Potential energy of each state

A

Gases: 0 potential energy
Liquid: Negative electrostatic potential energy
Solid: Large negative electrostatic potential energy

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15
Q

SHC definition

A

The energy required per unit mass to change the temperature of a substance by 1K

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16
Q

SHC units

A

J kg^-1 K^-1

17
Q

SHC equation

A

E=mcΔθ

18
Q

SLH definition

A

The energy required to change the phase of a material per unit mass while at a constant temperature

19
Q

SLH equation

A

E = mL

20
Q

SLH equation from a circuit

A

L = IVt/m

21
Q

Latent heat of fusion and vaporisation

A

Lf is between solid and liquid

Lv is between liquid and gas

22
Q

Lv and Lf comparison

A

Lv is usually > Lf as the difference in internal energy between liquids and gases is usually more than between solids and liquids

23
Q

Measuring Lv and Lf

A

For Lf connect ice at melting point to a heating circuit
For Lv connect a substance at boiling point to a heating circuit and connect to a condenser
Use L =IVt/m

24
Q

Potential energy changes without a state change

A

A small increase as the temperature increases