Chapter 14 concepts Flashcards

1
Q

Diluted Alcohols

A

Because they lack hydrogen bonding, they will have a sharper absorption

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2
Q

Symmetry

A

No change in bond dipole, no bond dipole

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3
Q

Ester vs ketone

A

Ketone’s sp3 CH has a higher wave number

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4
Q

vinylic ch

A

3100

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5
Q

why 2 signals for 12 sp3?

A

symmetric and asymmetric

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6
Q

degenerate

A

same energy level

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7
Q

hydrogen bond

A

dipole dipole

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8
Q

protic

A

one h bond to electronegative atom

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9
Q

frequency is directly proportional to

A

energy

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10
Q

frequency is inversely proportional to

A

wavelength

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11
Q

wavelength is inversely proportional to

A

energy

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12
Q

electromagnetic spectrum

A

gamma, x, uv, visible, ir, microwave, radio

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13
Q

radio

A

highest wavelength

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14
Q

gamma

A

highest frequency

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15
Q

ir tells you

A

functional groups

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16
Q

mr tells you

A

arrangement of c and h

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17
Q

uv vis spectroscopy

A

conjugated pi bond

18
Q

absorption of ir results in

A

vibrational excitement of the bonds in a compound, stretching and bending

19
Q

location of signal

A

wavenumber

20
Q

warm objects

A

emit more ir

21
Q

wavenumber unit

A

cm -1

22
Q

stretching virbration

A

directly proportion to strength, inversely proportional to reduced mass

23
Q

vibration must result in

A

change of bond dipole

24
Q

primary amines have

A

symmetrical and asymmetrical stretching

25
Q

Molecular ion

A

positively charged ion produced by ionization technique

26
Q

base peak corresponds to

A

must abundant ion

27
Q

molecular ion is produced by

A

loss of one electron

28
Q

whats produced when a compound is bombarded with high energy electrons

A

radical cations

29
Q

mass spectrometry would be used to determine

A

molecular formula and weight

30
Q

OH

A

3200-3600

31
Q

Carboxylic Acid

A

2200-3600, 1650-2000

32
Q

sp

A

3300

33
Q

Amine

A

3350-3500

34
Q

sp2

A

3000-3100 3000-3100

35
Q

sp3

A

2850-3000

36
Q

Aldehyde

A

2750-2800

37
Q

Ketone

A

1650-1820

38
Q

C=C

A

1600-1700

39
Q

C≡C

A

2100-2200

40
Q
A