Chapter 13: Equilibrium Flashcards
equilibrium
rate of the forward reaction and rate of the reverse reaction occurring at the same rate
forward and reverse reactions continue to occur: dynamic equilibrium
reversible reactions
proceed in forward and reverse directions
reaction quotient
describes the status of a reaction
varies as the reaction proceeds towards equilibrium
Qc=Kc
Qc>Kc, reaction will produce more reactants
Qc<Kc, reaction will produce more products
equilibrium constant
ratio of the rate constants of each step on the mechanism
homogenous equilibria
all reactants and products are in the same phase
occur in solution, either liquid or gas
heterogeneous equilibria
reactants and products are in two or more phases
coupled equilibria
reverse: reciprocal
doubled: raise to power of two
combine: multiply constants
Le Chatelier’s principle
if an equilibrium system is stressed, the system will shift in the direction to restore equilibrium