Chapter 13 Flashcards

1
Q

How do you convert from celcius to kelvin?

A

add 273

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2
Q

What is absolute 0?

A

0K or -273*C. Where all particles have the minimum possible kinetic energy

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3
Q

What is Boyle’s Law?

A

At a constant temperature, the pressure p and volume V of a gas are inversely proportional. pV=constant. True for ideal gases

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4
Q

What is Charles’ Law?

A

At constant pressure, the volume V of a gas is directly proportional to its absolute temperatre. V/T=constant. True for ideal gases

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5
Q

What is the pressure law?

A

At constant volume, the pressure p of a gas is directly proportional to its absolute temperature. p/T is constant. True for ideal gases

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6
Q

What is the ideal gas equation for moles of gas?

A

pV=nRT, where p is pressure, V is volume, n is number of moles, R is molar gas constant (8.31J/mol/K) and T is temperature in kelvin

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7
Q

What is the Boltzmann’s constant?

A

The gas constant for one particle of gas. k=R/N(a)=1.38x10^-23

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8
Q

What is the equation of state of an ideal gas?

A

pV=NkT, where p is pressure, V is volume, N is number of particles, k is Boltzmann’s constant and T is temperature in kelvin

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9
Q

What is the equation from the kinetic theory of a gas?

A

pV=1/3 Nmc^2, where p is pressure, V is volume, N is number of particles, m is mass of an individual particle and c^2 should have a bar over it and is the mean square speed: the average of all the speeds squared.

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10
Q

What is the rms speed?

A

The root mean square speed. The square root of the mean square speed, which is the speed of all the particles squared, and then averaged.

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11
Q

What are the 7 simplifying assumptions in the kinetic theory model?

A

1) Gas contains a large number of particles
2) The particles move rapidly and randomly
3) The motion of the particles follows Newton’s laws
4) Collisions between particles themselves or at the walls of the container are, on average, perfectly elastic
5) There are no attractive forces between particles
6) Any forces that act during collisions are instantaneous
7) Particles have a negligible volume compared with the volume of the container
If does all these things, it is an ideal gas

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12
Q

When do real gases behave like ideal gases?

A

When the pressure isn’t too big and the temperature is reasonably high, compared with their boiling points

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13
Q

What is specific thermal capacity?

A

The amount of energy required to raise the temperature of 1kg of a substance by 1K

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14
Q

Describe the speed distribution of gas particles

A

Particles don’t all travel at the same speed. Goes up to peak at modal speed, then plateauing to axis. As temperature changes, the area under the graph is constant, but peak moves to right and downwards

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15
Q

What is the internal energy of a substance?

A

The sum of the kinetic and potential energy of the particles within.

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16
Q

How do you calculate the internal energy of a sample of an ideal, monatomic gas?

A

U = N/2 mc^2 = 3/2 nRT = 3/2 NkT, where m is mass, c^2 should have a bar and is mean square speed, n is number of moles, R is molar gas constant, N is number of particles, k is Boltzmann’s constant and T is temperature.

17
Q

How do you calculate the energy of a gas particle in a sample of gas?

A

E=kT (it is of the order of this)

18
Q

How can you estimate the rms speed of a gas molecule?

A

1/2 mc^2 = 3/2 kT

19
Q

How can the internal energy of a material be changed?

A

By doing work or by thermal transfer of energy. change in internal energy, delta U = W + Q

20
Q

What is unusual about water?

A

Has a very high specific thermal capacity. Means oceans regulate global temperature as they heat up and cool down slowly