Chapter 12- Kinetic Equations

Question 1

Rate law for zero order reaction

Answer 1

Rate = K

Question 2

Rate law for first order reaction

Answer 2

Rate = K[A]

Question 3

Rate law for second order reaction

Answer 3

Rate = K[A]^2

Question 4

Integrated rate law for zero order reaction

Answer 4

[A]=-kt+[A]o

Question 5

Integrated rate for first order reaction

Answer 5

ln[A]=-kt+ln[A]o

Question 6

Integrated rate for second order reaction

Answer 6

1 = kt + 1
—- —-
[A] [A]o

Question 7

Plot needed to give a straight line for a zero order reaction

Answer 7

[A] vs. t

Question 8

Plot needed to give a straight line for a first order reaction

Answer 8

ln [A] vs. t

Question 9

Plot needed to give a straight line for a second order reaction

Answer 9

[A]

Question 10

Relationship of rate constant to the slope of straight line

For a zero order reaction

Answer 10

Slope = – K

Question 11

Relationship of rate constant to the slope of straight line

For a first order reaction

Answer 11

Slope = – K

Question 12

Relationship of rate constant to the slope of straight line

Answer 12

Slope = K

Question 13

Half-life for a zero order reaction

Answer 13

t (1/2) = [A]o
——-
2K

Question 14

Half-life for a first order reaction

Answer 14

t (1/2) = 0.693
——-
K

Question 15

Half-life for a second order reaction

Answer 15

t (1/2) = 1
——-
K [A]o