Chapter 11 Flashcards
Molarity (M)
mol of solute / L of solution
Molality (m)
mol of solute / kg of solvent
Mass Percent (m/m%)
mass of solute / mass of solution * 100%
Parts Per Million (ppm)
mass of solute / mass of solution * (1*10^6)
Parts Per Billion (ppb)
mass of solute / mass of solution * (1*10^9)
Mole Fraction (X)
mol of solute / mol of solution
Volume Percent (v/v%)
mL of solute / mL of solution
Dispersion
Non-polar (6th Strongest)
Dipole Induced Dipole
Polar To Nonpolar (5th Strongest)
Ion Induced Dipole
Ion To Non Polar (4th Strongest)
Dipole-Dipole
Polar To Polar (3th Strongest)
H-Bonds
Hydrogen Bonds To N, O, Or F (2th Strongest)
Ion Dipole
Ion To Polar Molecule (1th Strongest)
Exothermic
ΔH = Negative / Creates Energy From The Reaction / Goes Down
Endothermic
ΔH = Positive / Used Energy For The Reaction / Goes Up
When You Increase Temperature (Exo/Endo)
Endothermic - increased solubility / Exothermic - decreased solubility
Solute - Solute (Strong)
Endothermic
Solute - Solute (Weak)
Exothermic
Polar In Polar / Non Polar In Non Polar
Exothermic Or Endothermic / Has To Be Close Together / Stronger Interaction
Polar In Non Polar
Endothermic / Dispersion Weak / Big Difference
Water Soluble For Gas
Low Temperature
High Pressure
Henry’s Law Constant
Contraction Of Gas (moles) = Henry’s Law Constant (moles/pressure) * Partial Pressure Of Gass (atm)
Raoult’s Law
Vapor Pressure Of The Solution = Mole Fraction Of The Solvent * Vapor Pressure Of The Pure Solvent
Van ‘t Hoff Factor
Amount Of Concentration / Multiple It To Molarity & Molality
Vapor Pressure Depends On
Number Of Particles / Strength Of Intermolecular Forces
When Using Kb
You Need To Muttiply By How Many Ions Will Be Created
Change In Temperature (Equation)
Change In Temperature = boiling/freezing constant * concentration in molaity * Van’t Hoff Factor
The Lower Henry’s Law Constant
The Lower The Vapor Pressure Lower Soulbity In Water
Volitional Dissolving
Volitial - Exothermic
Nonvolitial - Endothermic
Osmotic Pressure
Osmotic Pressure = Van’t Hoff Index * Molarity * Ideal Gas Constant * Temperature In Kelvin
Celsius To Kelvin
Add 273.15