Chapter 10 Flashcards
charge carriers
electrons, electron holes, anions, cations
which material has the highest conductivity
metals, then semiconductors
types of semiconductors
Silicon, Germanium
conductivity of ceramics
mostly low, except for a few (Fe3O4 and RuO2)
conductivity of polymers
low
rank materials from most to least resistive
insulators
semiconductors
metallic
superconductor
what happens to the electron distribution in a partially filled band when temperature increases
electrons begin to shift and spread out (representative of metallic behavior)
Fermi-Dirac Statistics
occupancy is higher the higher the temperature
energy band diagrams for conductors
no gap at all
partially filled valence band at 0 K
energy band diagrams for semiconductors
small gap
completely filled valence band at 0 K
Eg <= 2.5
energy band diagrams for insulators
large gaps
completely filled valence band at 0 K
Eg > 2.5
charge carriers for metals
electrons
N is constant
q is constant
mu ~ (1/T)
charge carriers for semiconductors
electrons and holes
N increases with increasing temperature
charge carriers for insulators
anions, cations, electrons, and holes
N increases with increasing temperature
q varies according to charge carrier
factors that affect conductivity in metals
vacancies, foreign atoms, thermal vibrations
influence of alloying in conductivity
alloying decreases conductivity
influence of cold working on conductivity
decreases conductivity
number of charge carriers in insulators
depends exponentially on temperature
carrier transferrence number
t= sigma(carrier)/sigma(total)
n-type conductivity
an extra electron from a group V donor atom hovers in the gap along the Ed line
extrinsic
p-type conductivity
an electron hole created by an atom with less electrons hovers in the gap along the Ea line
extrinsic
Define: E(g) DeltaE, mu(e) mu(h) N
Eg=band gap DeltaE=impurity energy levels mu_e=electron mobility mu_h=hole mobility N=carrier density
Dopants for Silicon
P, Sb, Al, Ga
Dopants for Ga As
Se, Cd