Chapter 1: Portland Cement Chemistry Flashcards
What is Portland Cement responsible for
Responsible for binding aggregate together = producing concrete
Portland Cement is made from what 3 elements
Limestone, clay, gypsum
Cement composition
SiO2, Al2O3, Fe2S3, CaO, MgO, So3
ASTM C150 what are the 5 types of cement
Type 1: general use
Type 2: moderate sulfate resistant
Type 3: high early strength
Type 4: low heat of hydration
Type 5: high sulfate resistant
What are the 4 cement composition
C2S
C3S
C3A
C4AF
C2S
Dicalcium Sulfate
C3S
Tri calcium Sulfate
C3A
Tri calcium aluminate
C4AF
Tetracalcium aluminate
What are the 3 main cement chemical hydrations equations
C2S + h20 = CH + CSH
C3S + h20 = CH + CSH
C3A + h20+ gypsum = Ettringite
What is CH
Calcium Hydroxide
What is CSH
Calcium Silicate Hydrate
Why does normal concrete stay plastic (workable) for a few hours ?
Takes time for cement to get supersaturated, having to produce ions, needing about 4 hours to hydrate and have chemicals bond together
What are the 4 hydration stages
- Initial
- Dormant
- Acceleration
- Deceleration
Impact of SCM - retarders
Increase stage 2
Impact of SCM - Accelerators
Push the saturation process
Impact of SCM - Accelerators
Push the saturation process
Differences of pozzolanic
Reacts with CH to produce CSH