Chapter 1 Flashcards

1
Q

Internuclear Distance

A

The distance between two nuclei

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2
Q

Electronegativity

A

How strongly an atom attracts shared electrons

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3
Q

Covalent bonds

A

electrons shared between two atoms, where electronegativity difference is less than 0.5

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4
Q

Polar bonds

A

electrons shared between two atoms with electronegativity difference between 0.5 and 1.7

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5
Q

Ionic bonds

A

The electrons are not really shared, the two atoms
differ in electronegativity by more than 1.7, and so the more electronegative atoms own the electrons

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6
Q

Wave function

A

functions that relate the locations of an electron in a given point in space to the amplitude of a wave, which corresponds to its energy

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7
Q

Wave equation

A

an expression describing the position of an electron in space and time

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8
Q

Atomic Orbital

A

a function describing the location and wave-like behavior of an electron in an atom.

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9
Q

electron density

A

used to refer to the probability of finding an electron

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10
Q

Node

A

a point or plane of zero electron density in an orbital

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11
Q

Aufbau principle

A

dictates the manner in which electrons are filled in the atomic orbitals of an atom in its ground state. It states that electrons are filled into atomic orbitals in the increasing order of orbital energy level.

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12
Q

Pauli exclusion Principle

A

No two electrons can hold the same direction in orbital space, one arrow up one arrow down

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13
Q

Hund’s rule

A

Every orbital must be singly occupied before another electron is placed into it. All up arrows before and down arrows

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14
Q

Constructive interference

A

When the max of two waves come together to form a larger wave

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15
Q

Destructive interference

A

When waves come together to cancel each other out

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16
Q

Sigma bonds

A

the bonded electrons that are overlapping in the atomic orbital space

17
Q

Steric Number

A

the number of atoms bonded to a central atom of a molecule plus the number of lone pairs attached to the central atom

18
Q

Protic solvent

A

when a hydrogen atom is bonded to an oxygen, fluorine, or nitrogen atom

19
Q

Aprotic

A

incapable of acting as a proton donor

20
Q

Temporary Dipole

A

when there is a lot of random motion within a molecule that results in an uneven balance of the positive charge of the nuclei

21
Q

If Steric number is 4

A

sp3

22
Q

if Steric number is 3

A

sp2

23
Q

If steric number is 2

A

sp

24
Q

H-Bonding

A

the attractive forces between a H bonded to an electronegative atom ( N, O, F ) and a lone pair on another electronegative atom

25
Q

Molecular geometry

A

describes only the atoms bonded to the central atom