Chap. 10: pH, Acids, and Bases Flashcards
pH
Per Hydrogen.
The measure of the concentration of H+ in a solution.
Acid
Donate H+ ions into a solution.
For example:
HCl → H+ + Cl-
Acids also come in different strengths. The more moles of H+, the stronger the acid.
Base
There are two ways to define bases:
1.) Put OH- into a solution.
NaOH → Na+ + OH-
2.) Remove H+ from a solution.
NH3 + H2O ⇔ NH4+ + OH-
H+ Ions
Acidic.
Increase in H+, decrease in OH-.
OH- Ions
Basic.
Increase in OH-, decrease in H+.
pH and Water
Water and H+ and OH- will go back and forth with each other until a state of equilibrium is reached.
H2O ⇔ H+ + OH-
or
H2O + H2O ⇔ H3O+ + OH-
(Both of these are correct, both are used)
pH Scale
Acidic (more H+ ions) = pH of -1 to 6
101 = –1 (concentrated HCl)
100 = 0 (battery acid)
10-1 = 1 (lemon juice)
10-3 = 3 (vineger, soft drink, beer)
10-4 = 4 (tomato, coffee)
10-5 = 5 (urine, rainwater)
10-6 = 6 (milk)
*Neutral* 10-7 = 7 (pure water, blood, seawater)
10-8 = (seawater)
10-9 = 9 (baking soda)
10-10 = 10 (soap)
10-11 = 11 (ammonia)
10-12 = 12 (hair remover)
10-13 = 13 (oven cleaner)
Basic (more OH- ions) = pH of 8 to 14
Acids and Bases
HCl + NaOH → H2O (l) + NaCl
*This is also a double-displacement reaction.
1 mole HCl + 1 mole NaOH → 1 mole H2O
2 moles HCl + 4 moles NaOH → Basic
pH = -log10[H+]
H2O ⇔ H+ + OH-
1 in every 10 million water molecules are reacting this way. Therefore:
pH = -log10[H+]
What is the pH of a solution that has a hydronium-ion concentration of 0.001M?
The number 0.001 is 10-3 (by moving the decimal point three places to the right), therefore:
pH = – log [H3O+]
= – log [10-3]
= – ( –3)
pH = 3
What is the pH of a 0.01M solution of HCl?
The number 0.01 is 10-2 (by moving the decimal point two places to the right), therefore:
pH = – log [H3O+]
= – log [10-2]
= – ( –2)
pH = 2
What is the pH of a 0.000001M solution of HCl?
The number 0.0000001 is 10-6 (by moving the decimal point six places to the right), therefore:
pH = – log [H3O+]
= – log [10-6]
= – ( –6)
pH = 6
What is the pH of a 0.01M solution of NaOH?
Since NaOH is a base, we are going to start from the basic end of the pH Scale.
0.01M is 10-2
Starting from the very basic 14, we subtract 2 to get the pH.
pH = 12