Ch5 Flashcards
Diffusion
Mass/material transport by atomic motion
Mechanisms of diffusion of gases/liquids
random (Brownian) motion
Mechanisms of diffusion of solids
vacancy diffusion or interstitial diffusion
Case Hardening
Diffuse carbon atoms into the host
iron atoms at the surface
Result of Case Hardening?
The presence of C
atoms makes iron (steel) harder
Self-diffusion
In an elemental solid, atoms migrating from one position to the other
Interdiffusion
In an alloy, atoms tend to migrate from regions of high concentration to regions of low concentration
What are the two types of diffusion mechanisms?
- Vacancy
- Interstitial
What is the driving force behind diffusion?
Concentration gradient
Thermal energy
Flick’s 1st Law
- Rate of diffusion independent of time
- Flux proportional to concentration gradient
Flick’s 2nd Law
- The concentration of diffusing species is a function of both time
and position C = C(x,t) - Define boundary conditions
Flick’s 1st Law deals with
steady-state diffusion
Flick’s 2nd Law deals with
non-steady-state diffusion
Expanding D formula. What is D?
diffusion coefficient [m^2/s]
Expanding D formula. What is D_o?
pre-exponential [m/s^2]