Ch5 Flashcards

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1
Q

Diffusion

A

Mass/material transport by atomic motion

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2
Q

Mechanisms of diffusion of gases/liquids

A

random (Brownian) motion

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3
Q

Mechanisms of diffusion of solids

A

vacancy diffusion or interstitial diffusion

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4
Q

Case Hardening

A

Diffuse carbon atoms into the host
iron atoms at the surface

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5
Q

Result of Case Hardening?

A

The presence of C
atoms makes iron (steel) harder

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6
Q

Self-diffusion

A

In an elemental solid, atoms migrating from one position to the other

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7
Q

Interdiffusion

A

In an alloy, atoms tend to migrate from regions of high concentration to regions of low concentration

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8
Q

What are the two types of diffusion mechanisms?

A
  1. Vacancy
  2. Interstitial
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9
Q

What is the driving force behind diffusion?

A

Concentration gradient
Thermal energy

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10
Q

Flick’s 1st Law

A
  1. Rate of diffusion independent of time
  2. Flux proportional to concentration gradient
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11
Q

Flick’s 2nd Law

A
  1. The concentration of diffusing species is a function of both time
    and position C = C(x,t)
  2. Define boundary conditions
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12
Q

Flick’s 1st Law deals with

A

steady-state diffusion

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13
Q

Flick’s 2nd Law deals with

A

non-steady-state diffusion

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14
Q

Expanding D formula. What is D?

A

diffusion coefficient [m^2/s]

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15
Q

Expanding D formula. What is D_o?

A

pre-exponential [m/s^2]

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16
Q

Expanding D formula. What is Q_d?

A

activation energy [J/mol or eV/atom]

17
Q

Expanding D formula. What is R?

A

gas constant [J/mol-K]

18
Q

Expanding D formula. What is T?

A

absolute temperature [K]