Ch2 Chemical Equilibrium Flashcards
KC
[A}^a [B]^b
Kc is unaffected by
change in concentration
presence of a catalyst
change in pressure
Kc affected by
temperature
How to measure equilibrium
pH meter
change in colour
change in electrical conductivity
Why titration can’t measure equilirbium
removal of H+ ions causes equilibrium to rebalance
only can be used when equilibrium is slow to form
Experimental methods condition
- equilibrium must not be disturbed by any measurement taken
- position must be determined by measuring physical property
Partial pressure
pressure that would be exerted by a gas in a mixture if it occupied the same volume on its own at the same temperature
Sum of partial pressure of components in equilibrium = total pressure
Partial pressure formula
mole fraction of gas x total pressure of equilibrium mixture
Mole fraction
amount in moles of a component in a mixture divided by the total amount of all components in moles in the mixture
Kp
[PA]^a [PB]^b