ch161 organic Flashcards by kylini Unknown | Brainscape

Q

1,3 – Keto Acids to enols

A

heat

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Q

enols to haloketone

A

halogen, H+

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Q

silyl enol ether to haloketone

A

halogen

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Q

lithium enolate to silyl enol ether

A

Me3SiCl

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Q

ketone to lithium enolate

A

LDA

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Q

ketone to sodium carboxylate

A

halogen, NaOH

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Q

ketone to ketal

A

H+/alchohol
PADPED

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Q

alkyne to ketone

A

Hg(OAc)2 /H2O

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Q

alkyne to boroalkene

A

BH3
Syn

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Q

alkyne to haloalkene

A

Anti,
halogen /HX

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Q

alkyne to alkene

A

H2, Pt/C
Syn

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Q

alkene to hydroxyhaloalkene

A

halogen, H2O

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Q

alkene to alkane

A

H2/ Pt

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Q

alkene to diol

A

Syn
OsO2
H2O

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Q

alkene to epoxide

A

Syn
RCO3H

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Q

alkene to haloalkane

A

HX/heat, UV, peroxide = AM
HX/X2 = M
Anti

Q

haloalkane to ether

A

SN1 reaction

Q

alkene to ether

A

alcohol
SN1 reaction

Q

alkene to boroalkane

A

BH3
Syn

Q

alkene to hydroxymercurane

A

Hg(OAc)2 /H2O