ch161 organic Flashcards
1
Q
1,3 – Keto Acids to enols
A
heat
2
Q
enols to haloketone
A
halogen, H+
3
Q
silyl enol ether to haloketone
A
halogen
4
Q
lithium enolate to silyl enol ether
A
Me3SiCl
5
Q
ketone to lithium enolate
A
LDA
6
Q
ketone to sodium carboxylate
A
halogen, NaOH
7
Q
ketone to ketal
A
H+/alchohol
PADPED
8
Q
alkyne to ketone
A
Hg(OAc)2 /H2O
9
Q
alkyne to boroalkene
A
BH3
Syn
10
Q
alkyne to haloalkene
A
Anti,
halogen /HX
11
Q
alkyne to alkene
A
H2, Pt/C
Syn
12
Q
alkene to hydroxyhaloalkene
A
halogen, H2O
13
Q
alkene to alkane
A
H2/ Pt
14
Q
alkene to diol
A
Syn
OsO2
H2O
15
Q
alkene to epoxide
A
Syn
RCO3H
16
Q
alkene to haloalkane
A
HX/heat, UV, peroxide = AM
HX/X2 = M
Anti
17
Q
haloalkane to ether
A
SN1 reaction
18
Q
alkene to ether
A
alcohol
SN1 reaction
19
Q
alkene to boroalkane
A
BH3
Syn
20
Q
alkene to hydroxymercurane
A
Hg(OAc)2 /H2O
