CH1 summary vocab Flashcards

1
Q

chemical shift?

A

the position of an NMR signal

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

signal splitting is caused by?

A

spin-spin coupling

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what is signal splitting?

A

indicates the number of hydrogen atoms on adjacent carbons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

signal splitting follows what rule?

A

the n+1 rule

n= is the number of equivalent hydrogen atoms separated by three or fewer bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

chemical shifts can be described by what 2 ways?

A

higher frequency and lower frequency

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

higher frequency

A

toward larger ppm values

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

lower frequency

A

toward smaller ppm values

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

higher frequency signals result from ___ which is caused by

A

deshielding, caused by decreased density around the nucleus and electron withdrawing group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

lower frequency signals result from___which

A

shielding, caused by higher electron density around a nucleus and elecctron donating

How well did you know this?
1
Not at all
2
3
4
5
Perfectly