Ch1-4 Flashcards

1
Q

Functional group

A

Characteristic group of atoms/bonds that possess a predictable chemical behavior

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2
Q

Alkenes

A

Compound with a carbon-carbon double bonds

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3
Q

Alcohols

A

Compounds possessing an OH group

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4
Q

Amine

A

N-H

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5
Q

Ether

A

-O-

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6
Q

Aromatic

A

6 carbon ring with 3 double bonds

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7
Q

Amide

A

Carbon double bond to O and single bond to N

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8
Q

Carboxylic acid

A

Carbon double bond to oxygen and a single bond to hydroxide

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9
Q

Ester

A

Carbon double bond to oxygen and a single bond to oxygen

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10
Q

Vinylic

A

Two carbon atoms bearing the double bonds

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11
Q

Allylic

A

The atoms connected directly to the vinylic positions

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12
Q

Bronsted-lowry acids and bases

A

Acid is the proton donor

Base is the proton acceptor

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13
Q

Reaction mechanism

A

They show how the reaction occurs in terms of the motion of electrons

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14
Q

Equilibrium

A

There is no longer an observable change in the concentration of reactants and products

Rate of forward reaction = rate of reverse

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15
Q

K eq equation

A

Keq = [H3O+][A-] / [HA][H2O]

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16
Q

Ka equation

A

Ka = [H3O+][A-] / [HA]

Ka measures strength of acid

  • high Ka = strong acid
  • small Ka = weak acid
17
Q

pKa equation

A

pKa = -log Ka

Strong acid = low pKa
week acid = high pKa

pKa 10 vs 16 (6 orders of magnitude difference= 1 million)

18
Q

Electronegativity

A

How willing the atom is to except a new electron

19
Q

Ethane

A

H3-C-C-H3

20
Q

Ethylene

A

H2-C=C-H2

21
Q

Acetylene

A

H-C_=C-H

22
Q

Benzene

A

C6H6 circle

23
Q

Saturated hydrocarbons

Alkanes

A

Hydrocarbons that lack pie bonds

Names usually end with -ane

24
Q

Alkyl groups

A

Substituents or branches from parent

25
Q

Calorimeter

A

Experimental device used to measure heat of combustion

26
Q

Energy

A

Branched alkanes are lower in energy (more stable) than straight chain alkanes

27
Q

Petro-

A

Rock

28
Q

-Oleum

A

Oil

29
Q

Refining

A

The process of separating crude oil into commercially available products

30
Q

Degenerate

A

Same amount of energy

31
Q

Torsional strain

A

The difference in energy between staggered and eclipsed confirmation of ethane