Ch 22

Question 1

Simple cation

Simple anion

Answer 1

Simple compound

Question 2

Cation Anion

Complex Simple
Simple Complex
Complex Complex

Answer 2

Coordination compound

Question 3

Coordination compound

Answer 3

A salt that contains a transition metal

Question 4

monodentate

Answer 4

bites on one site only

ex. NH3, H2O, Halogens, CO

Question 5

ambidentate

Answer 5

bites on one site only, but can bond on either side

CN-, SCN-, NO2-,

Question 6

bidentate

Answer 6

attach to metal at two sites

ex. ethylenediamine (en), carbonate, oxalate

Question 7

polydentate

Answer 7

ethylenediaminetetraacetate ion

Question 8

chelating agents

Answer 8

break two bonds to release ligand from metal

attach/grab onto metal

Question 9

to be a _______ you have to break down at least __________ to release the ligand from the _______

Answer 9

chelating agent

2 bonds

metal

Question 10

EDTA4- is?

Answer 10

a preservative, also used in pepto bismal

Question 11

Coord. isomerism

Answer 11

same formula, different ingredient in complex ion

Question 12

linkage isomers

Answer 12

only apply ambidentate ligands

Question 13

stereoisomers

Answer 13

same formula, diff arrangement

Question 14

geometric isomers

Answer 14

molecules have same bond, different spacial arrangements

ALWAYS find 2 IDENTICAL pt of reference

Question 15

optical isomer

Answer 15

same formula, same bond, non superimposable mirror images
ex. hands
needs chiral center

Question 16

the ______ splitting in coord. complexes is the cause of both ________ and ___________ for these species

Answer 16

d-orbital

COLOR

MAGNETIC BEHAVIOR

Question 17

Why does the d-orbital split into sets?

Answer 17

its about the orientation of the orbital with respect to the direction of the approach of the ligand

Question 18

TRUE OR FALSE:

the more repulsive forces, the higher it is on the energy scale

Answer 18

true nigga

Question 19

what is the visible region of the electromagnetic spectrum

Answer 19

400-700nm

Question 20

what leads to absorption?

Answer 20

if the energy of the incoming photon is = to the crystal splitting parameter

Question 21

what determines the magnitude (size) of the crystal splitting parameter?

Answer 21

ligands

Question 22

magnetism

Answer 22

number of unpaired e-

Question 23

list the ligands from largest degree of splitting to smallest
and strongest field ligand to weak field ligand

Answer 23

CN- > NO2- > NH3 > H2O > F- > Cl- > Br- > I-

Question 24

what does it mean if something is low spin?

Answer 24

usually minimum unpaired e-

Question 25

what does it mean if something is high spin?

Answer 25

usually maximum unpaired e-

Question 26

diamagnetic

Answer 26

all e- paired

Question 27

paramagnetic

Answer 27

has unpaired e-