ch 20; shaping processes for plastics Flashcards
3 reasons plastic shaping processes are important
1) many of the processes are net shape processes
2) less energy is employed than in metalworking processes
3)lower temperatures needed to process plastics than metals or ceramics
4) greater flexibility in geometry
5) painting and other finishing processes not required generally
plastics require lower temperatures for processing compared to {} or {}. This is since plastics are composed of { p c}, that soften and become {} at relatively low temps.
metals, ceramics
long polymer chains
moldable
common thermoplastics like {} can be processed between around {}°C, while metals often require temperatures above {}°C to melt, and ceramics even higher for {si}
polyethylene, polypropylene
150-250
1000
sintering
plastics often have greater {} in geometry due to their moldability and {…} available. Processes such as {}, {} and extrusion allow for the creation of complex shapes with {i d }. Plastics can easily be molded into thin walls and {i d} that would be challenging for metals and ceramics. This flexibility makes plastics ideal from intricate {} devices and large { }
flexibility
variety of processing techniques
blow molding, injection molding
intricate detail
intricate detail
medical devices
automotive parts
4 main categories of plastic shaping processes, as classified by resulting product geometry
1) extrusion
2) molding
3) forming of continuous sheets and films
4) fibres
5) foamed products
what 3 parameters does the polymer melt’s viscosity depend upon
1) temperature
2) shear rate
3) molecular weight of polymer
how does viscosity of polymer melt differ from most Newtonian fluids?
polymer melt exhibits pseudoplasticity i.e. the viscosity decreases with increasing shear rate
(Newtonian fluids have const velocity regardless of shear rate)
why do polymers exhibit pseudoplasticity?
viscosity reduces as shear rate increases, long polymer chains align and disentangle under shear, reducing resistance to flow
viscoelastic meaning in context of polymer melt
viscous and elastic properties, cause melt to exhibit memory–tendency to return to previous shape, as exhibited by die swell in extrusion
briefly describe plastic extrusion process
polymer melt compressed to flow through die orifice and thus the continuous length of plastic assumes aa cross sectional shape the same as the orifice, approximately
identify and describe the three sections of the barrel and screw of an extruder
1) the feed section, feed stock fed from hopper and heated
2) compression section, polymer changes to a viscous fluid
3) metering section, pressure developed to pump the plastic through the die orifice
2 functions of the screen pack and breaker plate at the die end of the extruder barrel
1) filter dirt and lumps
2) build pressure
3) straighten the flow and remove memory of the polymer melt
3 forms of extruded shapes and corresponding dies
1) solid profiles e.g. rounds and L-shapes
2) sheet and film
3) filaments (continuous fibres)
4) wire and cable coating
what do sheet and film dies do
transform extruded molten polymer into thin, malleable masses via pressure into a sheet or film die
distinction between plastic sheet and film
thickness
sheet stock thickness> 0.5mm
film stock thickness<0.5 mm thick
what’s the blown film process for producing film stock
making thin polyethylene film for packaging
combines extrusion and blowing to produce tube of film
beings with extrusion of molten tube, that’s immediately drawn upward, simultaneously expanded in size by air inflated into it through the die mandrel
describe calendering process
producing sheet and film stock out of rubbery or rubbery thermoplastics, initial feedstock passed through series of rolls to work the material and reduce thickness to desired gage
example of a rubbery thermoplastic
plasticized PVC
most commercially important application in polymer fibres and filaments
textiles
difference between fibre and filament
fibre–long, thin stran of material, length»diameter (approx 100 times)
filament–fibre of continuous length
most important synthetic fibres…
Polyester first
nylon, acrylics, rayon