Ch 20/21 Flashcards
What reagents do you use for the following reaction?
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H2O
H2SO4 (catalyst)
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What reagents do you use for the following reaction?
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H20
HCl (Catalyst)
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What reagents do you use for the following reaction?
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H2NCH2CH3
2 equivalent
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What reagents do you use for the following reaction?
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CH3OH
CH3ONa
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What reagents do you use for the following reaction?
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MCPBA
HOSO2CF3
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What is the product of the following reaction?
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What is the product of the following reaction?
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Put the following in order for Aptitude for Migration with MCPBA
most likely to migrate –> least likely to migrate
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What reagents do you use for the following reaction?
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PROTECTING AMINE (STEP 1)
BOC2O
NaHCO2
DEPROTECTING AMINE (STEP 2)
TFA
CF3COH2
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What reagents do you use for the following reaction?
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H2N-R’
DCC
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What reagents do you use for the following reaction?
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HO-R’
DCC
DMAP
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What reagents do you use for the following reaction?
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1) NaOCH3, HOCH3
2) CH3CO2H
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What reagents do you use for the following reaction?
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1) NaOH, H2O
2) CH3CO2H
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What reagents do you use for the following reaction?
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1) NaOCH2CH3
2) CH3CO2H
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When do you use BOC protecting group?
Why?
To protect an amine group from reacting - ensuring an OH group does react
amines are more basic and nucleophilic compared to alcohols