Ch. 2: The Chemical Context of Life Flashcards

1
Q

Matter

A

anything that has mass and takes up space

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2
Q

Pure Substance

A

elements and compounds

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3
Q

Element

A

cannot be broken down further (ex: H)

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4
Q

Compound

A

a substance composed of two or more elements; can be broken down further (ex: H2O)

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5
Q

Trace Elements

A

required in only minute (very small) quantities

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6
Q

Atom

A

smallest unit of matter that still retains the properties of an element

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7
Q

Which elements compose ~96% of living matter?

A

Oxygen (O), Carbon (C), Hydrogen (H), and Nitrogen (N)

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8
Q

Subatomic Particles

A

particles that compose atoms; protons, neutrons, electrons

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9
Q

Neutron

A

neutral charge

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10
Q

Proton

A

positive charge

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11
Q

Electron

A

negative charge

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12
Q

Atomic Nucleus

A

dense core where protons and neutrons are packed tightly; electrons surround an atom, forming a cloud

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13
Q

What is the atomic mass unit (amu)?

A

Dalton

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14
Q

Atomic Number

A

number of PROTONS in an element; tells the number of protons AND electrons in an element (because they balance each other out, so must be equal); ex: 2He means 2 protons in helium nucleus (Helium is second element on periodic table)

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15
Q

What does the atomic number dictate?

A

The location of an element on the periodic table (ex: Oxygen has an atomic number of 8, making it the 8th element on the periodic table)

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16
Q

Mass Number

A

total number of protons and neutrons in a nucleus

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17
Q

How do you find the number of neutrons?

A

Subtract the atomic number from the mass number (ex: 4/2 He, 4-2 = 2 neutrons)

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18
Q

Atomic Mass

A

total mass of an atom

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19
Q

What will all isotopes always have the same number of?

A

they will always have the same number of protons as the original element

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19
Q

Isotopes

A

different atomic forms of the SAME element

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20
Q

Radioactive Isotope

A

nucleus decays spontaneously, releasing particles and energy, which can serve as tracers to track atoms

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21
Q

Half-Life

A

“parent” isotope decays into its “daughter” isotope at a FIXED rate; the time it takes for 50% of the isotope to decay

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22
Q

How does potential energy vary with distance? (relating to electrons and nucleus)

A

the more distant an electron is from the nucleus, the greater potential energy there is

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23
Q

Electron Shells

A

each has a characteristic average distance to the nucleus; the first shell closest to the nucleus has the lowest potential energy

24
How do electrons move between shells?
when an electron absorbs energy, it moves to a shell farther out from nucleus; when it loses energy, it moves to a shell closer to the nucleus
25
How many electrons can the first shell hold?
No more than 2; the maximum is 2
26
How many electrons can the second shell hold?
a maximum of 8
27
Which shell is most responsible for the chemical behavior of an atom?
the outermost shell (valence shell) and the number of electrons it has
28
Valence electrons
electrons on the outermost shell
29
Valence shell
outermost electron shell
30
What happens when an atom has a completed valence shell?
it is unreactive; inert
31
Orbital
the 3-dimensional space where an electron is found 90% of the time; a component of electron shell
32
How many electrons can occupy a single orbital?
no more than 2
33
How many electrons can the four orbitals of the second shell hold?
8 electrons
34
Chemical Bond
attraction that holds atoms together
35
Covalent Bond
the sharing of a pair of valence electrons by two atoms
36
Molecule
two or more atoms held together by covalent bonds
37
Single Bond
one pair of shared electrons
38
Double Bond
2 pairs of shared electrons
39
Valence
bonding capacity; usually equal to the number of electrons required to complete the atom's outermost (valence) shell
40
What does valence generally determine?
how many covalent bonds that atom will form
41
Electronegativity
the attraction of a particular atom for the electrons of a covalent bond; atoms attract shared bonding electrons to varying degrees
42
How does electronegativity affect the pull of shared electrons?
The more electronegative an atom is, the more strongly it pulls shared electrons toward ITSELF; it wants to bring them closer
43
Nonpolar Covalent Bond
a covalent bond between two atoms of the SAME element in which the electrons are shared EQUALLY since the atoms have the same electronegativity
44
Polar Covalent Bond
when one atom is bonded to a more electronegative atom, so the electrons of the bond are not shared equally (they are pulled closer to the atom with greater electronegativity)
45
Ions
atoms or molecules that have an electrical charge
46
Cation
ion w/ positive charge
47
Anion
ion w/ negative charge
48
Ionic Bond
attraction between cations and anions; any two ions of opposite charge can form an ionic bond
49
Ionic Compounds (Salts)
compounds formed by ionic bonds; they do not consist of molecules
50
How does an ion become a cation?
loses an electron
51
How does an ion become an anion?
gain an electron
52
Hydrogen Bond
noncovalent attraction between a hydrogen atom and an electronegative atom
53
van der Waals interactions
occur only when atoms and molecules are very close together, enables atoms and molecules to stick to each other; individually weak
54
Reactant
starting material in a chemical reaction
55
Product
resulting material in a chemical reaction
56
What happens during chemical reactions?
matter is conserved; it cannot be destroyed or created, only electrons can be rearranged
57
Chemical Equilibrium
the point at which the reactions offset one another EXACTLY