CH 17

Question 1

Naming: benzene with -CH3

Answer 1

toluene

Question 2

Naming: benzene with -OH

Answer 2

phenol

Question 3

Naming: benzene with -OCH3

Answer 3

anisole

Question 4

Naming: benzene with-NH2

Answer 4

aniline

Question 5

Naming: benzene with -C=C

Answer 5

styrene

Question 6

Naming: benzene with -CHO

Answer 6

benzaldehyde

Question 7

Naming: benzene with -COOH

Answer 7

benzoic acid

Question 8

Naming: benzene with -COC

Answer 8

acetophenone

Question 9

when benzene is a subst. on a larger molecule it is called a ?

Answer 9

phenyl

Question 10

Huckel’s rule: in order to be aromatic, cmpds should be ?

Answer 10

planar, cyclic, and fully conjugated polyenes that posses 4n+2pi e- where n is an integer

Question 11

antiaromatic molecules are?

Answer 11

planar, monoculic fully conjugated polyenes that posses 4npi electrons

Question 12

what position is the most stable

Answer 12

benzylic

Question 13

secondary and tertiary subst. at the benzylic position will form ? product

Answer 13

E2

Question 14

reagents to oxidize benzylic position to COOH if have at least 1 H

Answer 14

KMNO4
or
Na2Cr2O7, H2SO4, H20

Question 15

Reagents for Birch Reduction

Answer 15

Na/Li/K, NH3
EtOH