ch 13 for EXAM 3 Flashcards
colligative prosperities
physical characteristics of a solution that depends on the number of particles dissolved in a solution
vapor pressure
the pressure of gas above a liquid when they are in dynamic equlilbrium
volatile
evaporates easily
nonvolatile
does not evaporate easily
the addition of a non-volatile solute ___ the amount of solvent per unit volume, therefore ____ molecules escape
-reduces
-fewer
after adding a non-volatile solute, which reduces the rate of vaporization, the equilibrium is
re-established but with a smaller number of vapor molecules, so the vapor pressure is lower
when a pure solvent and a concentrated solution is places under a bell jar…
the solvent molecules will evaporate from each jar, establishing a new equilibrium
-in the pure solvent, the level drops
-in the concentrated solution, the level of solution rises
with a bell jar experiment, the net transfer btw the beakers indicates
the vapor pressure of the solution is lower than the pure solvent
the thirsty concentrated solution grabs and holds solvent vapor…
more effectively and becomes LESS concentrated
raoults law
vapor pressure of a solution is directly proportional to the mole fraction of the solvent for NON-ELECTROLYTE and NON-VOLATILE SOLUTES
ideal solution
solute-solute, solvent-solvent = solutle-solvent
raoules law for ionic compounds (electrolyte solutions) equation
Xc= (moles of solvent)/ (moles of solvent + i x moles of solute)
vapor pressure lowering occurs at
all temperatures
freezing point depression
results in the temperature required to freeze a solution being lower than the freezing point of the pure solvent
boiling point elevation
results in the temperature required to boil the solution being higher than the boiling point of the pure solvent
boiling point increases (w particles and vp)
-particles in solution increase
-vapor pressure decreases
osmosis
the passage of solvent through a semipermeable membrane from the less concentrated to the more concentrated side
during osmosis, the movement of the solvent through a semipermeable membrane increases the…
volume of the side of the concentrated solution
osmotic pressure π
the amount pf pressure necessary to cause osmosis to stop, or the amount of pressure to achieve an equilibrium passage pf solvent molecules through a semipermeable membrane
π =
iMRT
isotonic
-if 2 solutions have identical osmotic pressures
hypotonic
if one solution is of lower osmotic pressure its hypotonic with respect to the more concentrated solution
hypertonic
with respect to a dilute solution, the more concentrated solution is hypertonic
reverse osmosis
if the solution in contact with pure solvent separated by a semipermeable membrane is subjected to an external pressure greater than osmotic pressure