ch 13 for EXAM 3 Flashcards

1
Q

colligative prosperities

A

physical characteristics of a solution that depends on the number of particles dissolved in a solution

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2
Q

vapor pressure

A

the pressure of gas above a liquid when they are in dynamic equlilbrium

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3
Q

volatile

A

evaporates easily

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4
Q

nonvolatile

A

does not evaporate easily

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5
Q

the addition of a non-volatile solute ___ the amount of solvent per unit volume, therefore ____ molecules escape

A

-reduces
-fewer

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6
Q

after adding a non-volatile solute, which reduces the rate of vaporization, the equilibrium is

A

re-established but with a smaller number of vapor molecules, so the vapor pressure is lower

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7
Q

when a pure solvent and a concentrated solution is places under a bell jar…

A

the solvent molecules will evaporate from each jar, establishing a new equilibrium
-in the pure solvent, the level drops
-in the concentrated solution, the level of solution rises

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8
Q

with a bell jar experiment, the net transfer btw the beakers indicates

A

the vapor pressure of the solution is lower than the pure solvent

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9
Q

the thirsty concentrated solution grabs and holds solvent vapor…

A

more effectively and becomes LESS concentrated

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10
Q

raoults law

A

vapor pressure of a solution is directly proportional to the mole fraction of the solvent for NON-ELECTROLYTE and NON-VOLATILE SOLUTES

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11
Q

ideal solution

A

solute-solute, solvent-solvent = solutle-solvent

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12
Q

raoules law for ionic compounds (electrolyte solutions) equation

A

Xc= (moles of solvent)/ (moles of solvent + i x moles of solute)

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13
Q

vapor pressure lowering occurs at

A

all temperatures

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14
Q

freezing point depression

A

results in the temperature required to freeze a solution being lower than the freezing point of the pure solvent

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15
Q

boiling point elevation

A

results in the temperature required to boil the solution being higher than the boiling point of the pure solvent

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16
Q

boiling point increases (w particles and vp)

A

-particles in solution increase
-vapor pressure decreases

17
Q

osmosis

A

the passage of solvent through a semipermeable membrane from the less concentrated to the more concentrated side

18
Q

during osmosis, the movement of the solvent through a semipermeable membrane increases the…

A

volume of the side of the concentrated solution

19
Q

osmotic pressure π

A

the amount pf pressure necessary to cause osmosis to stop, or the amount of pressure to achieve an equilibrium passage pf solvent molecules through a semipermeable membrane

20
Q

π =

21
Q

isotonic

A

-if 2 solutions have identical osmotic pressures

22
Q

hypotonic

A

if one solution is of lower osmotic pressure its hypotonic with respect to the more concentrated solution

23
Q

hypertonic

A

with respect to a dilute solution, the more concentrated solution is hypertonic

24
Q

reverse osmosis

A

if the solution in contact with pure solvent separated by a semipermeable membrane is subjected to an external pressure greater than osmotic pressure