Ceramics Flashcards

1
Q

Define a ceramic.

A

An inorganic compound of 1 metal and 1 or more non-metals. [Ionic and covalent bonding possible.]

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2
Q

Define silica

A

SiO2, main ingredient in most glass products.

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3
Q

Define alumina

A

Al2O3, used in abrasives and fake bones

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4
Q

Define hydrous aluminum silicate

A

Main ingredient of clay

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5
Q

What are the main properties of ceramics

A
High hardness
Electrical and Thermal Insulators
Chemically Stable
High Melting Temps
Brittle
No ductility
Sometimes translucent
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6
Q

Define the three categories of ceramics.

A

Traditional: Clay, abrasives, cement
New Ceramics: oxides, carbides (better mechanical properties than traditional)
Glasses: based on silica, noncrystalline

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7
Q

Why can’t ceramics absorb stresses like metals can?

A

Ionic&covalent bonding vs metallic bonding - no slip

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8
Q

How do you strengthen ceramics?

A
Make starting materials uniform
Decrease grain size
Decrease porosity
Introduce compressive surface stresses
Use fiber reinforcement
Heat treat
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9
Q

Are all ceramics insulators?

A

No - large range of electrical conductivities, but generally lower than metals.

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10
Q

Describe thermal expansion in ceramics

A

Less than in metals, but more damaging because of brittleness

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11
Q

What are traditional ceramics made of?

A

Mineral silicates, silica, alumina, and other clay and cements found in nature. Glass is sometimes defined as a traditional ceramic because it is also a silica product.

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12
Q

Where do you get silica naturally?

A

Quartz, from sandstone. It’s low cost, hard, and chemically stable.

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13
Q

Where do you get alumina from?

A

Bauxite and corundum. It has good hot hardness, low thermal conductivity, and good corrosion resistance.

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14
Q

What differentiates new ceramics from traditional?

A

Chemically simpler, and developed synthetically.

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15
Q

Define glass, first as a state of matter, and then as a ceramic.

A

As a state of matter, glass is the amorphous structure of a solid material. It occurs when molten materials are cooled into solids to fast to become crystalline.
As a ceramic, glass is a compound that cools to a rigid condition without crystallizing.

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16
Q

Why is silica used for glass?

A

It naturally cools to it’s glassy state rather than crystallizing.

17
Q

Why are there other ingredients besides silica in glass?

A

They promote fusion during heating, they increase fluidity in molten glass, they improve chemical resistance to acids bases and water, they add colour, and alter optic index of refraction.

18
Q

How are glass-ceramics formed?

A

Heat treatment. They use smaller grains. (makes them stronger than original ceramics). Are generally opaque, not clear.

19
Q

What are the advantages of glass ceramics?

A

Close dimensional control over final shape
High strength (stronger than glass)
Low porosity and thermal expansion
High resistance to thermal shock

20
Q

What are the elements that act like ceramics?

A

Carbon
Silicon
Boron

21
Q

What is the relationship in ceramics between strength and porosity?

A

UTS = UTSo e^-nP
P = porosity
n is an exponent factor
As porosity goes up, strength goes down. Exponentially.

22
Q

Is carbon conductive? Graphene oxide?

A

Carbon - yes

Graphene Oxide - no