Ceramic system Flashcards
What are ceramics?
Compounds of metallic and non-metallic elements: most frequently oxides, nitrides and carbides
What are traditional ceramics?
China, porcelain, bricks, tiles, glasses
What are the 2 forms of silica?
Amorphous and crystaline
What is the ceramic building block?
Silica SiO2
What are examples of
a) crystalline
b) amorphous silica?
Crystaline e.g. quartz and cristoballite
Amorphous e.g. Alumino-silicate glasses
What is dental ceramic made up of
Mixture of both amorphous and crystaline
What was the composition of early dental porcelain?
Ground sea shell - Feldspar 73-85% K2O, Al2O3, 2SiO2
Sand - Quartz, 13-25%, Al2O3 2SiO2
Clay - Kaolin, SiO2, 0-4%
What are the different dental ceramics?
Feldspathic glasses Leucite reinforced feldspathic glasses Alumina reinforced feldspathic glasses Lanthanum glass infiltrated alumina Pure alumina Zirconia Glass ceramics
What do we use feldspathic glasses for?
To make the outside of the crowns with, know it is relatively weak
What are the different dental glass ceramics?
Mica
Lithium disilicate
Canasite
Apatite/Mulite
What is the dental ceramic processing?
Sintering
Casting
Hot processing
CAD-CAM machining
Because feldspathic ceramic is weak, what 3 ways can it gain support
Metal substructure e.g. pfm
High strength cermic substructure - have zirconia
Bond to the tooth, so tooth is substructure e.g resin bonded crown
What is the baseline aesthetic restoration (the one all others are compared to)
Metal ceramic restorations
In simple terms, how is the metal substructure processed?
Lost wax casting process
In simple terms, how is the cermic veneer made?
Ceramic sintering
In detail what is the production process of the metal substructure?
Take model of prepated tooth (dye)
Mock up cement layer underneath
Put layer of wax over the top
Alter the margins, design the substructure
Look in compatision to adjacent teeth
Wax then converted into metal
Put on sprew and funnel, place a casting ring around it and fill with plaster of paris
Heat up in casting crucible
Shoot metal into mould - wax is converted into metal
Trim up to condition the surface for the ceramic to bond to the surface
In detail what is the production for the ceramic veneer to go on top of the metal substructure?
Take the powders and mix with modelling liquid
Paint the first opaque layer on, fire in the furniss, put on opaque proper to mask out the underlying metal substructure
3 firings:metal, first opaque then second opaque
Put the ceramic proper on and build up full contour then fire
The trim do fits, mark contact points
Put glaze on ceramic
What are the problems with metal-ceramic production?
Not enought space
How much tooth reduction is needed for pfm crown/
1.5mm
0.5mm for metal substructure
1mm for ceramic veneer
What are the clinical metal-ceramic problems?
Aesthetics
Metal substructure prevents light transmittance
Often appear opaque at the cervical 1/3
Metal margin can be seen - could overbuild the ceramic but this could cause blanching of the gingiva
What are the technical problems with metal-ceramic?
Metal-ceramic bond is tempremental
Metal-ceramic junction - abrasive and unhygienic
Metal-ceramic compatibility - thermal expansion co-efficient, shrinkage of materials when cooled down to room temp, if shrink at different rates they will fall apart
support fot ceramic can be well made or not
how is the thermal expansion co-efficient different in ceramic and metal?
When unbonded, and when bonded?
TECceramic20 degrees
To prevent the ceramic veneer from cracking due to different TEC’s what can be done?
TEC of ceramic must be equal or slightly less that that of metal therefore can ass leucite