Ceramic capacitors Flashcards
Basic components in MLCC
- Metallic electrodes
- Dielectric ceramic
- Connecting terminals
- Plating (Ni or Sn)
Classification of ceramic capacitors
- Class 1: use paraelectric materials
- Class 2: use ferroelectric materials
2 paraelectric materials used for class 1 ceramic caps and relative permittivity
- Magnesium niobium oxide (MgNb2O6): 21
- Magnesium tantalum oxide (MgTa2O6): 28
Example of 1 ferroelectric material used for class 2 ceramic caps and relative permittivity
- Barium titanate (BaTiO3) + additives (aluminium, magnesium, aluminium oxide): 5000
Information specified by electrical industry alliance for class II MLCCs
- Low T limit: X (-55°C), Y or Z
- High T limit: 4 to 9 (200°C)
- Change of C over T range: P,R,L,S,T,U,V
Materials used for internal and termination electrodes in MLCC
Internal:
- Noble metal: (Silver palladium) Ag-Pd alloy
- Base metal: Nickel (Ni)
Termination
- Substrate: Ag and Cu
- Barrier: Ni
- External: Sn
What is the most common termination style for MLCC today and why?
- Base metal electrodes that uses Cu and Ni
- It replaced Ag and Pd electrodes due to lower cost of Cu and Ni
Main steps of MLCC fabrication (Thomas pag 15)
- Start from ceramic powder
- Ceramic slurry
- Tape casting
- Sheet cutting
- Screen printing
- Stacking
- Lamination
- Dicing/cutting
- Binder burnout and sintering
- Termination
- Termination firing
- Test
Define ferroelectricity
- Property of certain nonconducting materials that exhibit spontaneous electric polarization that can be reversed in direction by the application of an appropriate E field
Explain in more detail spontaneous electric polarization of ferroelectric materials
- separation of the centre of positive and negative electric charge, making one side of the crystal positive and the opposite side negative
What happens in a ferroelectric material when the external E field is reversed?
- It reverses the predominant orientation of the ferroelectric domains, though the switching to a new direction lags somewhat behind the change in the external E field.
- This lag of electric polarization behind the E field is ferroelectric hysteresis
Under which condition, ferroelectricity of a material stops?
- For high T (above Curie T) because heat agitates dipoles enough to overcome forces that spontaneously align them
Other characteristics of ferroelectric materials
- Pyroelectricity (V is generated due to T changes)
- Natural electrical polarization is reversible
- spontaneous nonzero polarization (polarization even without E field)
- Polarization dependent on current E field and history (hysteresis loop)
- Saturation leading to decrease in permittivity as DC V increases
Classification of dielectric based on induced polarization vs E field (draw the curves) (Thomas pag 20)
- Linear dielectric polarization
- Paraelectric polarization (non-linear)
- Ferroelectric polarization (non-linear)
Explain pyroelectricity and its main characteristics
- Temporary V is generated when material is heated or cooled
- T change modifies slightly the position of the atoms, changing the polarization
- If T stays constant, V disappears due to leakage I (electrons moving in the crystal, ions moving through air, I leaking through voltmeter)
- Property of crystal that are naturally electrically polarized, hence contain large E fields
Equation for capacitance of MLCC
C = ere0(n-1)*A/d
n: number of stacked inner electrodes
Explain temperature dependence of class 2 caps: X7R, Z5U, Y5V based on the curves (Thomas pag 30)
Capacitance change with T
- X7R decreases then increases and again decreases with T
- Z5U decreases with T
- Y5V increases then decreases with T
Explain frequency dependence of class 2 caps (Thomas pag 30)
Capacitance decreases with frequency (X7R and Y5V)
Explain T and frequency dependence of class 1 caps
Capacitance is almost constant with T and frequency (NP0)
Draw the change of capacitance against frequency and T for class 1 (NP0) and class 2 (X7R, Y5V) caps (Thomas pag 30)
Draw on paper
Variation of barium titanate dielectric constant vs T (draw on paper) (Thomas pag 31)
- Overall dielectric constant increases with T
5 failure modes of ceramic caps
- Cracking
- short-circuiting at low V in high impedance circuits. Appears as micro-cracks in the ceramic
- Due to moisture and polarizing V, electrolytic material transportaion from one electrode to the other happens (ion bridge) (ionic migration), thus leakage I increases and insulation R is reduced leading to breakdown
- Corrosion damages electrodes surfaces thus increasing ESR and reducing C
- Very thin conductive path is easily burnt away if V exceeds rated values
List the 4 different defects in ceramic caps
- Manufacturing defects
- Flex crack (formed by excess bending of an MLCC)
- Thermal shock crack
- Placement cracks
Why is flex crack a severe problem?
- The defect only turns into failure (short circuit) in the field after the cap is exposed to humidity
- cannot always be detected electrically or visually
How the conductive path is formed at the flex crack? draw an schematic
- Due to the combination of flex cracks, humidity, applied voltage and time
- moisture penetration reduces insulation R of dielectric
- Eventually breakdown or short circuit occurs