cement Flashcards

1
Q

how is cement formed

A

limestone+shales»clinker (when heater)

|&raquo_space;add gypsum to clinker» cement

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2
Q

name the 4 clinker compositions and what the do

A

C3S- early strength
C2S-long term strength
C3A-initial setting
C4A-controlls melting in kiln

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3
Q

describe what happens when cements hydrated

A

1-particles dissolve and ions rearrange in the solution phase
2-solid hydrate phases solidify and give strength

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4
Q

name the 4 hydrate phases

A

1-C-S-H
2- calcium hydroxide
3-Aft (ettringite )
4-Afm

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5
Q

describe C-S-H

A
  • formed from the hydration of C3S and C2s
  • fills the space
  • non crystaline
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6
Q

describe calcium hydroxide

A
  • by product of the hydration of c2s and c3s

- HOLDS INTERNAL PH HIGH helping durability of the steel

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7
Q

explain ettringite Aft

A
  • formed from reaction of C3A+water+gypsum
  • needle shaped crystals interlocking gives initial setting
  • too much gypsum added» false set
  • too little» flash set
  • forms Afm too quick and has no strength
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8
Q

Afm

A

gives slight strength

can cause durability probs- sulphate attack which causes binder to expand>cracking

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9
Q

what a supplementary cementation materials and give an example

A

-added to alter the properties of binder improving performance
eg limestone
-pozzolans are SCM but contain Si or Al or fly ash

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10
Q

how do pozzolans form

A

cement blended with sources of Si0
-which react with CH»CSH
increasing strength and durability

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11
Q

are pozzolanic reactions slower or faster than hydration and whats the effects

A

slower then hydration»> gives strength at later stages/enhances long term properties

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