cement Flashcards
how is cement formed
limestone+shales»clinker (when heater)
|»_space;add gypsum to clinker» cement
name the 4 clinker compositions and what the do
C3S- early strength
C2S-long term strength
C3A-initial setting
C4A-controlls melting in kiln
describe what happens when cements hydrated
1-particles dissolve and ions rearrange in the solution phase
2-solid hydrate phases solidify and give strength
name the 4 hydrate phases
1-C-S-H
2- calcium hydroxide
3-Aft (ettringite )
4-Afm
describe C-S-H
- formed from the hydration of C3S and C2s
- fills the space
- non crystaline
describe calcium hydroxide
- by product of the hydration of c2s and c3s
- HOLDS INTERNAL PH HIGH helping durability of the steel
explain ettringite Aft
- formed from reaction of C3A+water+gypsum
- needle shaped crystals interlocking gives initial setting
- too much gypsum added» false set
- too little» flash set
- forms Afm too quick and has no strength
Afm
gives slight strength
can cause durability probs- sulphate attack which causes binder to expand>cracking
what a supplementary cementation materials and give an example
-added to alter the properties of binder improving performance
eg limestone
-pozzolans are SCM but contain Si or Al or fly ash
how do pozzolans form
cement blended with sources of Si0
-which react with CH»CSH
increasing strength and durability
are pozzolanic reactions slower or faster than hydration and whats the effects
slower then hydration»> gives strength at later stages/enhances long term properties