CCP Chemistry 121, Brauner Test 2 Flashcards

1
Q

What is the speed of light?

A

C = 3.0x108 m/s

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2
Q

What is Planck’s constant?

A

h = 6.626x10-34 J·s

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3
Q

What is Avagadro’s number?

A

N = 6.022x1023 /mol

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4
Q

What is a wavelength?

A

λ = the distance between two successive corresponding points

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5
Q

c = ****λ · **v

A

λ = c / **v

c = **↑λ · ↓v**

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6
Q

Ionization Energy

A

energy requried to remove 1 e-

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7
Q

Emission

A

The release of radiation when an e` goes from a higher energy state to a lower energy state

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8
Q

Energy

A

Ability to do work

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9
Q

Potential Energy

A

energy associated with matter due to it’s position

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10
Q

Kinetic Energy

A

energy associated with a body in motion

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11
Q

Velocity

A

V=distance/time

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12
Q

Frequency

A

“nu”, Number of ocillations/seconds

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13
Q

Charge of an electron

A

1.6x10^-19 Coulombs

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14
Q

Absorption

A

The use of radiation to promote an e` from a lower energy state to a higher energy state.

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15
Q

Ocillating electric charges…

A

…produce an electromagnetic wave.

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16
Q

Alternating current

A

the flow of electric charge periodically reverses direction

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17
Q

Direct Current

A

the flow of electric charge goes in one direction

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18
Q

Alpha Partical

A

+2He 2+

Helium nucleus

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19
Q

Beta Particle

A

e~

(negative charge)

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20
Q

Gamma Particle

A

**Photon - **

neutral charge

highest energy

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21
Q

Powers of 10

A

Moving decimal to the left?

Positive exponent.

Moving decimal to the right?

⇒Negative exponent.

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22
Q

K.E. =

A

K.E.=1/2mv2

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23
Q

Electrochemistry

A

A branch of physical chemistry that studies chemical reactions at the interface of an electrode and an ionic conductor.

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24
Q

Planck/Einstein Equation

A

l change in E I = hc/wavelength

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25
Q

Chromium

A

Correct: Cr = [Ar]4s13d5

Predicted: Cr = [Ar]4s23d4

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26
Q

Copper

A

Correct: Cu = [Ar]4s13d10

Predicted: Cu = [Ar]4s23d9

27
Q

Hund’s Rule:

A

e~s enter orbitals of the same sublevel (p,d, or f) singley until each orbital contains 1e~, then pairing occours.

28
Q

Diamagnetic

A

lacking unpaired e~s

29
Q

Paramagnetic

A

Having unpaired e~s

30
Q

Main group atoms

A

These atoms are characterized by the filling (the last e~ by prediction) of S (2e~) and P (6e~) sublevels (8 main groups).

31
Q

Main Group Atoms

A

thoses atoms characterized by the filling (the last e~ by prediction) of “s” and “p” sublevels

32
Q

Transition Metals

A

those atoms characterized by the filling of “d” sublevels

33
Q

Lanthanides

A

those atoms characterized by the filling of the “4f” sublevel

34
Q

**Actinides **

A

Those atoms characterized by the filling of th e”5f” sublevel

35
Q

Metal

A

An atom that tends to loose 1 or more e~’s

“metalic”

m+ + e~

36
Q

Non-Metal

A

An atom that tends to gain 1 or more e~’s

“non-metalic”

x + e~ → x-

37
Q

Nobel Gas

A

An atom that neither tends to loose nor tends to gain an e~

38
Q

Atom Size

A

Radii of an atom increases going down the table and decreases going from left to right.

39
Q

Ionization Energy

A

(kJ/mol) it takes to ionize an atom increases going from left to right. Ionization energy decreases going from top to bottom of table.

40
Q

Metallic character

A

Metallic character decreases going from left to right. Metallic character increases going down the periodic table.

41
Q

Electronegativity

A

Electron affinity increases going left to right, and increases going from bottom to top of periodic table.

42
Q

Principal Quantum #

A

n = Distance from nucleus

1,2,3,4,5,6,7

43
Q

Azmuthal Quantum #

A

l = Shape of orbital

s,p,d,f

44
Q

Magnetic Quantum #

A

ml = Orientation of orbital

45
Q

**Spin Quantum # **

A

ms= Spin of electron,

ms= +1/2 or

ms=-1/2

46
Q

kB =

A

2.179X10-18J

47
Q

Ionization Energy Formula

(H, He+, Li2+)

A

En =-kB• z2 / n2

48
Q

e~ Density

A

The probability of finding an e~ in a given space summarized by the wave function

49
Q

Amplitude

A

The maximum vibration of an ocillation, measured from the position of equilibrium

50
Q

Sublevel

A

“l” a description of the nodal properties of an e~, the nodal shape

51
Q

Space

A

Volume

52
Q

n

A

Principal quantum number. 1,2,3,4,5,6, and 7

53
Q

n

A

** Principal quantum number.**

1,2,3,4,5,6, and 7.

54
Q

l

A

Azimuthal quantum #.

s=2e~

p=6e~

d=10e~

f=14e~

55
Q

ml

A

Orientation. Magnetic quantum #

1, 3, 5, 7

56
Q

ms

A

Spin quantum #.

+1/2

**or **

-1/2

57
Q

Outer e~ ‘s

A

The e~ ‘s in the highest occupied level.

58
Q

Chromium

A

Cr=[Ar] 4s13d5

59
Q

K

A

K=[Ar]4s1

60
Q

Ca

A

Ca=[Ar]4s2

61
Q

Energy in a Photon

A

E = hv

62
Q

Formula for Ionization Energy

A

En = - 2.179 x 10-18x (z)2 / (n)2

63
Q

Charge of an Electron

A

1.6 x 10-19 Coulombs