Catalysts

Question 1

Trimerisation

Answer 1

Ni(CO)2(PPh3)4

Co(CO)2(Cp)

Question 2

Metathesis

Answer 2

Grubbs type
Rh P(Cy)3
Furstner
Mo-Ph - (OSiPh3)3

Question 3

Coupling- Normal

Answer 3

Pd(PPh3)4

Pd2(dba)3

Question 4

Coupling- Oxidative

Answer 4

Pd(OAc)2

Reoxidant- Ag2CO3

Question 5

Carboxylation Nu

Answer 5

Pd(PPh3)4

Base NEt3

Question 6

Carboxylation Epoxide

Answer 6

[MLn]+ [Co(CO)4]-

Question 7

Carboxylation - paulson Khan

Answer 7

Rh’Cl(CO)
from [Rh’Cl(CO)2]2

or Co2(CO)8

Question 8

Heck- Normal and Carbonylative

Answer 8

Pd(PPh3)4

AND BASE (NEt3)

Question 9

Heck - Oxidative

Answer 9

Pd(OAc)2

Reoxidant 2CuX2 X=OAc
Base NEt3

Question 10

meyer schuster

Answer 10

V(O)(OR)3

R=SiPh3

Question 11

Allylic substitution

Answer 11

ML2

Pd(PPh3)2

Question 12

Rh based

Answer 12

Paulson Khan
Rh’Cl(CO)

Wilkinsons
RhP3Cl

Hydroformylation
HRh1CoP3

Monsanto process
Rh’I2(CO)2

Question 13

Wilkinsons

Answer 13

Rh’Cl(PPh3)3

Question 14

Hydroformylation

Answer 14

HRh’(CO)(PPh3)3

Question 15

Hydrocyanation

Answer 15

NiL4 l=PPh3

Question 16

monsanto

Answer 16

Rh’(I)2(CO)2

Question 17

Cativa

Answer 17

Ir’(I2)(CO)2

Question 18

Lucite

Answer 18

Pd(OAc)2
px2 benz based
HOTs

Question 19

Alfen

Answer 19

Al(Et3) high p

then low p high T

Question 20

SHOP

Answer 20

Ni(cod)2 +HO- C(O) –P(Ph2) - wierd h thing

H-Ni-P)O +gap/solv

Question 21

Polyethelene

Answer 21

Ni, Br2 (N2Ar2) +MaO –> N2Ar) NiH - gap/solv

Question 22

Wacker

Answer 22

PdCl4 2-