Catalyst Equations Flashcards

1
Q

What is the contact process?

A

The use of vanadium oxide catalyst to oxidise SO2 into SO3

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2
Q

What are the two steps of the contact process?

A

1) V2O5 + SO2 -> V2O4 + SO3

2) V2O4 + 1/2O2 -> V2O5

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3
Q

What ion catalyses the reaction:

S2O8^2- + 2I^- -> I2 + 2SO4^2-

A

Fe2+

Homogenous catalyst

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4
Q

What are the two equations that show the action of the Fe2+ catalyst? (With I2/S2O8)

A

1) S2O8^2- + 2Fe2+ -> 2Fe3+ + 2SO4^2-

2) 2Fe3+ + 2I- -> I2 + 2Fe2+

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5
Q

Which homogenous catalyst catalyses the reaction between C2O4^2- and MnO4-?

A

Mn2+

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6
Q

How does Mn2+ effect the reaction?

A

Speed up the rate by providing a positive ion for the two negatives to react with

It is a product of the reaction so as the reaction progresses it speed up

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7
Q

What two equations show the action of the Mn2+ catalyst? (MnO4-/C2O4^2-)

A

1) MnO4- + 4 Mn2+ +8H+ -> 5Mn3+ + 4H2O

2) 2Mn3+ + C2O4^2- -> 2Mn2+ + 2CO2

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8
Q

What transition metal ion reduces manganate ions into Mn2+ ions?

A

Fe2+

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9
Q

What is the overall redox equation for the reaction of MnO4- and Fe2+?

A

MnO4- + 8H+ + 5Fe2+ -> Mn2+ + 5Fe3+ + 4H2O

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10
Q

What is the overall equation for the reaction of potassium manganate and acidified sodium ethanedioate?

A

2MnO4- + 16H+ + 5C2O4 ^2- -> 2Mn2+ + 8H2O + 10CO2

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