Catalyst Equations Flashcards
What is the contact process?
The use of vanadium oxide catalyst to oxidise SO2 into SO3
What are the two steps of the contact process?
1) V2O5 + SO2 -> V2O4 + SO3
2) V2O4 + 1/2O2 -> V2O5
What ion catalyses the reaction:
S2O8^2- + 2I^- -> I2 + 2SO4^2-
Fe2+
Homogenous catalyst
What are the two equations that show the action of the Fe2+ catalyst? (With I2/S2O8)
1) S2O8^2- + 2Fe2+ -> 2Fe3+ + 2SO4^2-
2) 2Fe3+ + 2I- -> I2 + 2Fe2+
Which homogenous catalyst catalyses the reaction between C2O4^2- and MnO4-?
Mn2+
How does Mn2+ effect the reaction?
Speed up the rate by providing a positive ion for the two negatives to react with
It is a product of the reaction so as the reaction progresses it speed up
What two equations show the action of the Mn2+ catalyst? (MnO4-/C2O4^2-)
1) MnO4- + 4 Mn2+ +8H+ -> 5Mn3+ + 4H2O
2) 2Mn3+ + C2O4^2- -> 2Mn2+ + 2CO2
What transition metal ion reduces manganate ions into Mn2+ ions?
Fe2+
What is the overall redox equation for the reaction of MnO4- and Fe2+?
MnO4- + 8H+ + 5Fe2+ -> Mn2+ + 5Fe3+ + 4H2O
What is the overall equation for the reaction of potassium manganate and acidified sodium ethanedioate?
2MnO4- + 16H+ + 5C2O4 ^2- -> 2Mn2+ + 8H2O + 10CO2