Carbs And Lipids Flashcards
What are monosacharrides classification based on
- # of carbons
- Nature of carbonyl
Which sugars have chiral centers
-aldoses w/h +3 Cs
- ketoses w/h +4 Cs
in glucose … out of the 6Cs are chiral
4
in fructose… out of the 6 Cs are chiral
3
D- or L- configurations are decided by ?
Configurations of -OH at the C farthest from R-CO-R
In glucose which carbon is the highest asymmetric carbon ?
C5
Type of polysaccharides
Starch, Glycogen, Cellulose , Chitin, Proteoglycan, Glycoproteins, Peptidoglycan
What is starch? what twp polymers make up starch?
Mixture of glucose polymers
Amylose ( 20-25%)
Amylopectin (75-80%
structure of amylose?
linear chains with 1-4 linkage
left handed
Structure of amylopectin
linear chains with 1-4 linkage
-branches at every 24-30 residues with 1-6
Function of glycogen
Storage polysaccharides in animals
What is the structure of glycogen
every 8-12 residues have a 1-6 branch
Function of cellulose
key in plant cell walls
what makes cellulose vital in cell walls
rigidity and mechanical strength against osmotic stress
what is the structure of cellulose
linear homopolymer of b-d Glucose linked by beta 1-4 linkages
how do the chains lie in cellulose
side by side staggered
what do the chains in cellulose form
sheets
what are the three types of H-bonding in cellulose
intrastrand, interstrand and intersheet
why are the three H-bonding in cellulose key
provide strength and resistant to hydrolysis, insoluble
Where is chitin found
in exoskeleton of crustaceans insects and spiders
structure of chitin
similar to cellulose
beta 1-4 linkages
what do chitin have thats important
extended linear chains made of N-acetyl-glucosamine (GlcNAc)
what bonding is key in chitin
H-bonding similar to cellulose
What do Proteogylcans contain
glycosaminoglycans (GAGs)
what is the backbone of proteoglycans
Hyaluronic acid polymers
What are glycoproteins and their job
sugars on proteins
responsible for targeting, sorting, recognition, protection from degradation
Modifications by sugars are… encoded in DNA
NOT
What links sugars to proteins
Glycoprotein via glycosylation