Carboxylic Acids And Esters Flashcards

1
Q

What is the functional group of a Carboxylic acid?

A

COOH

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2
Q

What main groups form a Carboxylic acid?

A

-carbonyl: C=O
-hydroxyl: O-H

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3
Q

What is the suffix for a Carboxylic acid?

A

-oic acid

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4
Q

How do we name Carboxylic acids?

A

carbon atom of carbonyl group is counted as start of carbon chain

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5
Q

What is the suffix group for the functional group attached to benzene?

A

-Carboxylic acid

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6
Q

What is the solubility of Carboxylic acids?

A

can form hydrogen bonds with water molecules
completely soluble from 1-4 carbons

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7
Q

Why do Carboxylic acids have higher melting points?

A

form hydrogen bonds with other Carboxylic acids in solid state-higher melting point than alkanes of similar relative molecular mass

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8
Q

How can we identify a Carboxylic acid?

A

use thiele tube
measure melting point
compare with known values of melting points
ALTERNATIVE
measure pH to see whether it is an acid or not

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9
Q

What is derived from a Carboxylic acid?

A

an ester

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10
Q

How is an ester formed?

A

hydrogen from acid OH replaced by alkyl or aryl group

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11
Q

What is the general formula of an ester?

A

RCOOR

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12
Q

How do we name esters?

A

end of name based on parent acid (ethanoic acid > ethanoate)
first part of name from alkyl/aryl group (end of chain)

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13
Q

What are the features of short chain esters?

A

fairly volatile
pleasant fruity smells

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14
Q

What are short chain esters used for?

A

-flavourings
-perfumes
-plasticisers

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15
Q

What is a plasticiser?

A

added to polymers to make them more flexible

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16
Q

What are long chain esters?

A

Fats and oils

17
Q

Where is equilibrium in Carboxylic acids?

A

To the left as they are weak acids

18
Q

Are Carboxylic acids proton donors or acceptors?

A

proton donors

19
Q

What is produced when a carboxylic acid and sodium hydroxide react?

A

sodium -oate and water

20
Q

What is produced when a carboxylic acid and sodium carbonate?

A

sodium -oate and water and carbon dioxide